74971-93-0Relevant academic research and scientific papers
Synthesis and Stereomutation of Optically Active α-Cyanosulphoxides
Annunziata, Rita,Cinquini, Mauro,Colonna, Stefano,Cozzi, Franco
, p. 614 - 617 (2007/10/02)
Reaction of (-)-menthyl (S)-toluene-p-sulphinate with nitriles and lithium NN-di-isopropylamide (LDA) in 1:1:1 and 1:2:1 ratios affords optically active α-cyano- and α-cyano-β-imino-sulphoxides, respectively. α-Cyanobenzyl sulphoxide racemizes through a h
Thermal Dimerization of Sulfinyl Compounds
Furukawa, Mitsuru,Okawara, Tadashi,Noguchi, Yoshihide,Nishikawa, Masumi,Tomimatsu, Masahide
, p. 976 - 978 (2007/10/02)
The dimers (2a-c) of active methylene compounds were readily synthesized by heating the corresponding α-sulfinyl compounds (1a-c) in carbon tetrachloride or tetrahydrofuran in 14-90percent yields. Keywords---dimer of active methylene compound; sulfinylati
