749862-40-6Relevant academic research and scientific papers
Syntheses, characterization and x-ray structures of the first copper(I) and silver(I) complexes with ATT (ATT = 6-Aza-2-thiothymine)
Ghassemzadeh, Mitra,Pooramini, Mostafa Mohammad,Tabatabaee, Maasoomeh,Heravi, Majid M.,Neumueller, Bernhard
, p. 403 - 406 (2004)
The reaction of copper(I) chloride with 6-aza-2-thiothymine (ATT, 1) and triphenylphosphane in methanol/chloroform gives [(ATT)CuCl(PPh3)] (2) as a neutral complex. [(ATT)Ag(NO3)-(PPh3) 2]·MeOH (3) can be obtained by the reaction of 1 with silver(I) nitrate and triphenylphosphane in methanol/chloroform in excellent yields and the single crystals of 3 can be obtained from acetonitril solution. Both complexes were characterized by infrared spectroscopy, elemental analyses as well as by X-ray diffraction studies. Crystal data for 2 at -80°C: space group 12/a with a = 1859.3(1), b = 1143.2(1), c = 2208.2(1) pm, β = 104.84(1)°, Z = 8, R1 = 0.0355 and for 3 at -80°C: space group P21/c with a = 1344.1(1), b = 1553.6(1), c = 1977,3(3) pm, β = 105.26(1)°, Z = 4, R1 = 0.0436.
