749904-72-1Relevant academic research and scientific papers
Synthesis and optical resolution of aminophosphines with axially chiral C(aryl)-N(amine) bonds for use as ligands in asymmetric catalysis
Mino, Takashi,Tanaka, Youichi,Hattori, Youtaro,Yabusaki, Toshihiro,Saotome, Hiroaki,Sakamoto, Masami,Fujita, Tsutomu
, p. 7346 - 7353 (2007/10/03)
N-Aryl indoline-type aminophosphines 1a-c were obtained in good yields by a nucleophilic aromatic substitution (SNAr) reaction followed by silane reduction. Aminophosphine 1d was also prepared from 2,3- difluorobenzaldehyde (4) via dimethylhydr
