7500-80-3Relevant articles and documents
Diastereoselective Synthesis of Dibenzo[b,d]azepines by Pd(II)-Catalyzed [5 + 2] Annulation of o-Arylanilines with Dienes
Bai, Lu,Wang, Yan,Ge, Yicong,Liu, Jingjing,Luan, Xinjun
supporting information, p. 1734 - 1737 (2017/04/11)
An efficient method for the construction of dibenzo[b,d]azepines containing two distinct stereogenic elements in a highly diastereoselective fashion is described. The key of the [5 + 2] reaction is to form a π-allylpalladium species through sequential C-H
Synthetic Routes to Arylpyrido-azepines and -azepines.
Schofield, Joseph,Smalley, Robert K.,Scopes, David I. C.,Patel, Dalpat I.
, p. 1401 - 1426 (2007/10/02)
9-Phenyl-6-methoxy-5H-pyridoazepine and 9-phenyl-7-methoxy-5H-pyridoazepine have been obtained by arylation (PhLi) of 6,9-dimethoxy-5H-pyridoazepine and by photolysis of 6-azido-9-phenylquinoline in potassium methoxide-methanol-dioxan