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SYNTHESIS AND CHARACTERIZATION OF Rh3(μ-PPh2)3(CO)3(PPh3)2: A NOVEL TRIANGULAR RHODIUM CLUSTER
Billig, E.,Jamerson, J.D.,Pruett, R.L.
, p. C49 - C51 (1980)
Thermal decomposition of RhH(CO)(PPh3)3 (Ph = phenyl) in nonane at 120 deg C yielded a green solid in high yield.The complex was established as Rh3(μ-PPh2)3(CO)3(PPh3)2, (I), by X-ray crystallography.It was found to be coordinately unsaturated in the solid state and in solution.
