
Journal of Organometallic Chemistry p. C49 - C51 (1980)
Update date:2022-09-26
Topics:
Billig, E.
Jamerson, J.D.
Pruett, R.L.
Thermal decomposition of RhH(CO)(PPh3)3 (Ph = phenyl) in nonane at 120 deg C yielded a green solid in high yield.The complex was established as Rh3(μ-PPh2)3(CO)3(PPh3)2, (I), by X-ray crystallography.It was found to be coordinately unsaturated in the solid state and in solution.
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(1981)