75067-06-0

Basic information

• Product Name: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)
• Synonyms: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)
• CAS NO: 75067-06-0
• Molecular Formula: C₂H₆S*C₆H₁₄BCl
• Molecular Weight: 195.58
• Mol File: 75067-06-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)(CAS DataBase Reference)
• NIST Chemistry Reference: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)(75067-06-0)
• EPA Substance Registry System: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)(75067-06-0)

Safety Data

• RIDADR: 3265
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 75067-06-0(Hazardous Substances Data)

Upstream product

• 563-79-1 2,3-Dimethyl-2-butene 
• 63348-81-2 monochloroborane dimethyl sulfide complex 
• 75-18-3 dimethylsulfide 
• 36594-41-9 BH₂Cl*Et₂O 

Downstream Products

• 111-87-5 octanol 
• 4128-31-8 rac-octan-2-ol 
• 594-60-5 2,3-dimethylbutan-2-ol 
• 79200-91-2 (CH₃)2CHC(CH₃)2BCl₂(S(CH₃)2) 
• 79200-86-5 (CH₃)2CHC(CH₃)2BHCl(O(C₂H₅)2) 
• 5523-19-3 boron trichloride - methyl sulfide complex 
• 37099-64-2 [(1,1,2-trimethylpropyl)borane]2 

Relevant articles and documents

Synthesis and characterization of new 19-vertex macropolyhedral boron hydrides

The new boron hydride anions 10-R-B19H19- (R = H, Thx) were synthesized by the reaction of M2[B18H20] (M = Na, K) with HBRCl·SMe2 (R = H, Thx) or HBCl2·SMe2 in diethyl ether. The anions are comprised of edge-sharing, nido 10- and 11-vertex cluster fragments, and are characterized by their 11B, 11B{1H}, and 11B-11B COSY NMR spectra. The salt [(Ph3P)2N][B19H20]·0.5THF crystallized in the triclinic space group P1(a = 12.6344-(2) A, b = 13.5978(2) A, c = 14.1401(2) A; α = 77.402(2)°, β = 81.351(2)°, γ = 73.253(2)°). Possible synthetic pathways are discussed. The dianion B19H192- is formed by deprotonation of B19H20- with Proton Sponge (1,8-bis(dimethylamino)naphthalene) in THF, and is identified on the basis of its 11B, 11B{1H}, and 11B-11B COSY NMR spectra.