75069-86-2Relevant academic research and scientific papers
SYNTHESIS AND STRUCTURE OF THE NbIV METALLOCYCLE > (M = Nb, R = Me3Si) AND REDUCTIVE CLEAVAGE OF d0 ANALOGUES (M = Ti, Zr, OR Hf; R = H OR Me3Si) BY Na
Lappert, M.F.,Martin, T.R.,Milne, C.R.C.,Atwood, J.L.,Hunter, W.E.,Pentilla, R.E.
, p. C35 - C38 (1980)
Reaction of with o-C6H4(CH2MgCl)2 in THF yields the metallocyclopentene (Ia, R = Me3Si; Ib, R = H), as confirmed by single crystal X-ray diffraction for Ia (average = 72.4 deg); treatment of the isoleptic Zr compound
