SYNTHESIS AND STRUCTURE OF THE NbIV METALLOCYCLE > (M = Nb, R = Me3Si) AND REDUCTIVE CLEAVAGE OF d0 ANALOGUES (M = Ti, Zr, OR Hf; R = H OR Me3Si) BY Na

DOI: 10.1016/S0022-328X(00)94437-1

Source and publish data:

Journal of Organometallic Chemistry p. C35 - C38 (1980)

Update date:2022-08-03

Topics:

Authors:

Lappert, M.F.

Martin, T.R.

Milne, C.R.C.

Atwood, J.L.

Hunter, W.E.

Pentilla, R.E.

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Article abstract of DOI:10.1016/S0022-328X(00)94437-1

Reaction of with o-C6H4(CH2MgCl)2 in THF yields the metallocyclopentene (Ia, R = Me3Si; Ib, R = H), as confirmed by single crystal X-ray diffraction for Ia (average = 72.4 deg); treatment of the isoleptic Zr compound

Full text of DOI:10.1016/S0022-328X(00)94437-1

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