75091-85-9Relevant academic research and scientific papers
SYNTHESIS OF SOME ANALOGS OF ABSCISIC ACID FROM 3-CYCLOHEXENE-1-CARBALDEHYDE AND ITS METHYL HOMOLOGS
Gramenitskaya, V. N.,Koz'mina, E. A.,Golovkina, L. S.,Vul'fson, N. S.
, p. 1690 - 1695 (2007/10/02)
The E,E and Z,E isomers of 5-substituted 3-methyl-2,4-pentanedioic acids were synthesized from 3-cyclohexene-1-carbaldehyde and its methyl homologs.The possibilities of their production by the Reformatsky and Wittig reactions or by condensation of substituted 3-cyclohexene-1-carbaldehydes with diethyl β-methylglutaconate were investigated.It was shown that the last path makes it possible to obtain the Z,E isomers preferentially.
