75099-07-9

Upstream product

• 123363-96-2 4-(benzyloxy)tetrahydro-5,5-dimethyl-2H-pyran-2-carboxylic acid 
• 123363-95-1 <4-(benzyloxy)tetrahydro-5,5-dimethyl-2H-pyran-2-yl>-methanol 
• 123363-94-0 3-(benzyloxy)-2,2-dimethyl-5-hexen-1-ol 
• 100-44-7 benzyl chloride 
• 123363-92-8 2-<2-(benzyloxy)-1,1-dimethyl-4-pentenyl>-1,3-dioxolane 
• 123363-93-9 3-(benzyloxy)-2,2-dimethyl-5-hexenal 
• 67213-31-4 2-(2-hydroxy-1,1-dimethyl-4-pentenyl)-1,3-dioxolane 
• 420-37-1 trimethoxonium tetrafluoroborate 
• 75099-06-8 (2R*,4S*)-4-(benzyloxy)tetrahydro-5,5-dimethyl-2H-pyran-2-carboxamide 

Downstream Products

• 85199-44-6 N-<<(2R*,4S*)-4-(benzyloxy)tetrahydro-5,5-dimethyl-2H-pyran-2-yl>methoxymethyl>-α-acetoxyphenylacetamide 
• 85199-40-2 N-<<(2R*,4S*)-4-(benzyloxy)tetrahydro-5,5-dimethyl-2H-pyran-2-yl>methoxymethyl>-2-acetoxypropionamide 

Relevant academic research and scientific papers

STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-PEDERINE

A mild one-pot method for the synthesis of acyclic N-(1-methoxyalkyl)amides starting from carboxylic acid and methyl imidates has been developed and applied to the first total synthesis of (+)-pederine (1), a potent insect poison.Furthermore, the stereocontrolled total synthesis of 1 was also achieved by employing acid catalyzed double alkoxy-exchange reaction of N-(1-methoxyalkyl)amide group as key step.