75101-61-0

Upstream product

• 18535-43-8 (ClMn(CO)4)2 
• 18789-75-8 Trimethylsilyl-N-phenylthioamidodiphenylphosphin 
• 14100-30-2 pentacarbonylchloromanganese(I) 
• 14879-42-6 iodo(pentacarbonyl)manganese(I) 
• 14516-54-2 bromopentacarbonylmanganese(I) 
• 739-61-7 diphenyl(N-phenylthiocarbamoyl)phosphine 

Downstream Products

• 103190-08-5 Mn(CO)3((C₆H₅)2PC(S)NC₆H₅)((C₆H₅)3P) 
• 103190-09-6 Mn(CO)3((C₆H₅)2PC(S)NC₆H₅)((CH₃O)3P) 

Relevant academic research and scientific papers

SYNTHESE UND KOORDINATIONSVERHALTEN AMBIDENTER CHELATLIGANDEN. II. DARSTELLUNG UND CHARAKTERISIERUNG VON CARBONYLMANGAN(I)-KOMPLEXEN MIT ORGANOSUBSTITUIERTEN PHOSPHINO-DITHIOFORMIATEN ODER-THIOFORMAMIDEN ALS WEITERE LIGANDEN

reacts with the potassium diorganylphosphino-dithioformates or -thioformamides KS(X)CPR2 (X = S, NPh: R = Ph, Cy; Cy = cyclo-C6H11), respectively, to give the monomeric tetracarbonylmanganese(I) complexes (CO)4> (Ia-Id), whereas w

PHOSPHINSUBSTITUIERTE CHELATLIGANDEN I. MANGAN- UND RHENIUMCARBONYL-KOMPLEXE MIT PHOSPHINO-(THIO)FORMAMID- UND -DITHIOFORMIAT-LIGANDEN

A series of new tetracarbonyl and tricarbonyl complexes of manganese and rhenium with heteroallylic phosphine chelate ligands L = - and HXC(Y)PPh2 (X, Y = Nr, O, S) were prepared by reaction of the appropriate metal carbonyl halides with the free ligands or their silyl intermediates.The silyl method yields both cis-(CO)4ML and fac-(CO)3M(X)L (X = Cl, Br) complexes by controlled addition of water.Analytical, spectroscopic and crystallographic data of the ambidentate thioformamide ligands result in a P,S-coordination in all complexes.The 13C NMR spectra ofseveral selected compounds were recorded and reveal some unexpected features.