14100-30-2

Basic information

• Product Name: pentacarbonylchloromanganese
• Synonyms: pentacarbonylchloromanganese
• CAS NO: 14100-30-2
• Molecular Formula: C₅ClMnO₅
• Molecular Weight: 240.520949
• EINECS: 237-951-8
• Mol File: 14100-30-2.mol
• Article Data: 43

Chemical Properties

• Appearance: /
• CAS DataBase Reference: pentacarbonylchloromanganese(CAS DataBase Reference)
• NIST Chemistry Reference: pentacarbonylchloromanganese(14100-30-2)
• EPA Substance Registry System: pentacarbonylchloromanganese(14100-30-2)

Safety Data

• Hazardous Substances Data: 14100-30-2(Hazardous Substances Data)

Usage

InChI:InChI=1S/5CO.ClH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

Upstream product

• 56-23-5 tetrachloromethane 
• 10170-69-1 dimanganese decacarbonyl 
• 96-47-9 2-methyltetrahydrofuran 
• 75-05-8 acetonitrile 
• 463-71-8 thiophosgene 
• 15693-51-3 potassium[manganese(pentacarbonyl)] 
• 101-02-0 triphenyl phosphite 
• 52542-59-3 bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-) 
• 62554-44-3 ethyl 2-chloro-2-methylpropanoate 
• 185350-09-8 Mn(CO)5Re(CO)3(i-Pr-pyridine-2-carbaldehyde) 
• 75-09-2 dichloromethane 
• 97747-73-4 Mn(CO)5Re(CO)3(i-Pr-DAB) 
• 67-66-3 chloroform 
• 16972-33-1 pentacarbonylhydridomanganese 

Downstream Products

• 10170-69-1 dimanganese decacarbonyl 
• 16972-33-1 pentacarbonylhydridomanganese 
• 14872-96-9 {Mn(CO)3(NH₃)3}⁽¹⁺⁾*Cl^(1-)={Mn(CO)3(NH₃)3}Cl 
• 57-13-6 urea 
• 85688-54-6 {(palladium)(manganese)(Cl)(carbonyl)3(μ-dppm)2} 
• 60305-98-8 fac-{manganese(Cl)(carbonyl)3(dppm)} 
• 114594-81-9 fac-manganese(I)(carbonyl)3(dpmSe)Cl 
• 114594-87-5 (fac-manganese(I)(carbonyl)3(apeSe)Cl)2 
• 114594-91-1 fac-manganese(I)(carbonyl)3(apeSe)2Cl 
• 114594-82-0 fac-manganese(I)(carbonyl)3(dpmS)Cl 
• 31662-40-5 Mn(CO)4(P(C₆H₅)3)Cl 
• 14096-06-1 Mn(CO)3(P(C₆H₅)3)2Cl 
• 79703-04-1 Mn(CO)3(P(O(C₆H₅))3)2Cl 
• 85362-16-9 Mn(CO)4(P(O(C₆H₅))3)Cl 

Relevant articles and documents

Gas-phase reactions of ClMn(H2O)+ with polar and nonpolar hydrocarbons in a mass spectrometer

The gas-phase reactions of ClMn(H2O)+ with a variety of volatile and nonvolatile, saturated and unsaturated hydrocarbons have been examined by using Fourier transform ion cyclotron resonance mass spectrometry (FT/ICR). The ClMn(H2O)+ ion reacts rapidly by exclusive H2O ligand displacement with all the hydrocarbons studied, including highly branched alkanes that usually fragment upon ionization. These observations are rationalized on the basis of the electronic structure of ClMn+. Collision-activated dissociation of the product ions provides structural information which promises to allow the distinction and structural characterization of isomeric hydrocarbons. These findings suggest that the ClMn(H2O)+ ion is a highly promising chemical ionization reagent for mass spectrometric characterization of hydrocarbons, including those that commonly exist in petroleum. Copyright

Bismuth Compounds in Radical Catalysis: Transition Metal Bismuthanes Facilitate Thermally Induced Cycloisomerizations

The controlled radical chemistry of bismuth compounds is still in its infancy. Further developments are fueled by the properties of these complexes (e.g., low toxicity, high functional group tolerance, low homolytic bond dissociation energies, and reversible homolytic bond dissociations), which are highly attractive for applications in synthetic chemistry. Here we report the first catalytic application of transition metal bismuthanes (i.e. compounds with a Bi–TM bond; TM=transition metal). Using the catalyzed radical cyclo-isomerization of δ-iodo-olefins as a model reaction, characteristics complementary or superior to known B, Mn, Cu, Zn, Sn, and alkali metal reagents are demonstrated (including a different crucial intermediate), establishing transition metal bismuthanes as a new class of (pre-)catalysts for controlled radical reactions.

Therapeutic delivery of carbon monoxide

Compounds, pharmaceutical compositions and methods for the therapeutic delivery of carbon monoxide to humans and other mammals that employ Mn complexes having CO ligands, and additional halogen, monodentate and/or bidentate ligands, wherein the additional ligands do not occupy trans positions relative to each other.