75128-87-9Relevant academic research and scientific papers
Synthesis of benzannulated heterocycles by twofold Suzuki-Miyaura couplings of cyclic diarylborinic acids
Dimitrijevic, Elena,Cusimano, Madeline,Taylor, Mark S.
, p. 1391 - 1394 (2014/03/21)
Two-fold Suzuki-Miyaura cross-couplings of cyclic diarylborinic acids are described. This novel annulation method enables the synthesis of benzo-fused heterocycles from dihaloarenes or gem-dibromoolefins.
Organic Reactive Intermediates: Part XI - Preparation and Reactions of Xanthenyl Ylids
Handoo, Kishan L.,Kaul, Anju
, p. 1 - 2 (2007/10/02)
Two new xanthenyl ylids, viz. triphenylphosphoniumxanthen-9-ylid and triphenylphosphoniumthioxanthen-9-ylid have been prepared.The former undergoes normal Wittig reaction with a number of carbonyl compounds yielding olefins.
Studies on Betaine Decomposition of Arsonium Ylides
Tewari, R. S.,Suri, S. K.,Gupta, K. C.
, p. 95 - 98 (2007/10/02)
A systematic study on the nature of decomposition of betaine formed by nucleophilic attack of semistabilized arsonium ylides on thiocarbonyl substrates has been carried out.A series of substituted benzylidenetriphenylarsenanes have been generated from their corresponding salts and condensed with few cyclic thioketones to yield exocyclic olefins as exclusive products.The non-availability of thioepoxides indicates that the mode of decomposition of such type of betaines is quite analogous to the betaine formed by phosphonium ylides.The structure of the products have been assigned by IR and NMR spectral studies. - Keywords: Betaine, Arsonium Ylides
