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Extended Unsaturated Carbenes. Generation and Nature of Alkadienylidenecarbenes
Stang, Peter J.,Fisk, Thomas E.
, p. 6813 - 6816 (1980)
A simple, general means of entry into alkadienylidenecarbenes, R2C=C=C=C:, has been developed via base-initiated elimination of α-ethynylvinyl triflates.Trapping with tetramethylethylene results in cumulenes 10, whereas cyclohexene gives the dimer -rad
