Journal of the American Chemical Society p. 6813 - 6816 (1980)
Update date:2022-08-04
Topics:
Stang, Peter J.
Fisk, Thomas E.
A simple, general means of entry into alkadienylidenecarbenes, R2C=C=C=C:, has been developed via base-initiated elimination of α-ethynylvinyl triflates.Trapping with tetramethylethylene results in cumulenes 10, whereas cyclohexene gives the dimer <4>-rad
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