751445-01-9Relevant articles and documents
THE NOVEL FORMATION OF AN ACETONE ENOLATE COMPLEX VIA THE ADDITION OF METHYLLITHIUM TO THE ACYLRHODIUM(I) COMPOUND Rh(COMe)(CO)(triphos) (triphos=MeC(CH2PPh2)3)
Johnston, Gregory G.,Baird, Michael C.
, p. C51 - C54 (1986)
The compound Rh(COMe)(CO)(triphos) appears to react with methyllithium via addition to the acetyl carbon atom to form the complex (CO)(triphos)>(1-), rather than via the expected deprotonation of the acetyl group to form the enolate (ketene) c