THE NOVEL FORMATION OF AN ACETONE ENOLATE COMPLEX VIA THE ADDITION OF METHYLLITHIUM TO THE ACYLRHODIUM(I) COMPOUND Rh(COMe)(CO)(triphos) (triphos=MeC(CH2PPh2)3)

DOI: 10.1016/0022-328X(86)80382-5

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C54 (1986)

Update date:2022-08-02

Topics:

Authors:

Johnston, Gregory G.

Baird, Michael C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(86)80382-5

The compound Rh(COMe)(CO)(triphos) appears to react with methyllithium via addition to the acetyl carbon atom to form the complex (CO)(triphos)>(1-), rather than via the expected deprotonation of the acetyl group to form the enolate (ketene) c

Full text of DOI:10.1016/0022-328X(86)80382-5

Products guided by the article

Product name:Rh(CO)2(CH₃C(CH₂P(C₆H₅)2)3)^(1-)

Cas No:751445-01-9

R&D Labs maybe for 751445-01-9

New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)

Relevant to this article

Facile and Highly Stereoselective Synthesis of Homoallylic Alcohols Using Organosilicon Intermediates

Doi:10.1021/jo00101a021
(1994)
Copper(II) Acetylacetonate: An Efficient Catalyst for Huisgen-Click Reaction for Synthesis of 1,2,3-Triazoles in Water

Doi:10.1002/cjoc.201700007
(2017)
SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS (II). -PHOTOLYSIS OF UNSYMMETRICAL DIACYLPEROXIDES WITH ALKENYL-, HALO-, KETO-, CARBOXYL-GROUPS AND A CHIRAL α-CARBON. COMPARISON WITH THE MIXED KOLBE ELECTROLYSIS.

Doi:10.1016/S0040-4020(01)97195-9
(1985)
Doi:10.1002/jsfa.2740180206
(1967)
Palladium-Catalyzed N-Arylation of Sulfoximines with Aryl Sulfonates

Doi:10.1021/acs.joc.8b01599
(2018)
Metathesis of carbon dioxide and phenyl isocyanate catalysed by group(IV) metal alkoxides: An experimental and computational study

Doi:10.1007/s12039-011-0069-4
(2011)

Article Doi