THE NOVEL FORMATION OF AN ACETONE ENOLATE COMPLEX VIA THE ADDITION OF METHYLLITHIUM TO THE ACYLRHODIUM(I) COMPOUND Rh(COMe)(CO)(triphos) (triphos=MeC(CH2PPh2)3)

DOI: 10.1016/0022-328X(86)80382-5

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C54 (1986)

Update date:2022-08-02

Topics:

Authors:

Johnston, Gregory G.

Baird, Michael C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(86)80382-5

The compound Rh(COMe)(CO)(triphos) appears to react with methyllithium via addition to the acetyl carbon atom to form the complex (CO)(triphos)>(1-), rather than via the expected deprotonation of the acetyl group to form the enolate (ketene) c

Full text of DOI:10.1016/0022-328X(86)80382-5

Products guided by the article

Product name:Rh(CO)2(CH₃C(CH₂P(C₆H₅)2)3)^(1-)

Cas No:751445-01-9

R&D Labs maybe for 751445-01-9

Aqua Chem Industry Co., Ltd

Contact:+86-515-88356562

Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china

Relevant to this article

Facile and Highly Stereoselective Synthesis of Homoallylic Alcohols Using Organosilicon Intermediates

Doi:10.1021/jo00101a021
(1994)
Copper(II) Acetylacetonate: An Efficient Catalyst for Huisgen-Click Reaction for Synthesis of 1,2,3-Triazoles in Water

Doi:10.1002/cjoc.201700007
(2017)
SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS (II). -PHOTOLYSIS OF UNSYMMETRICAL DIACYLPEROXIDES WITH ALKENYL-, HALO-, KETO-, CARBOXYL-GROUPS AND A CHIRAL α-CARBON. COMPARISON WITH THE MIXED KOLBE ELECTROLYSIS.

Doi:10.1016/S0040-4020(01)97195-9
(1985)
Doi:10.1002/jsfa.2740180206
(1967)
Palladium-Catalyzed N-Arylation of Sulfoximines with Aryl Sulfonates

Doi:10.1021/acs.joc.8b01599
(2018)
Metathesis of carbon dioxide and phenyl isocyanate catalysed by group(IV) metal alkoxides: An experimental and computational study

Doi:10.1007/s12039-011-0069-4
(2011)

Article Doi