THE NOVEL FORMATION OF AN ACETONE ENOLATE COMPLEX VIA THE ADDITION OF METHYLLITHIUM TO THE ACYLRHODIUM(I) COMPOUND Rh(COMe)(CO)(triphos) (triphos=MeC(CH2PPh2)3)

DOI: 10.1016/0022-328X(86)80382-5

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C54 (1986)

Update date:2022-08-02

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Authors:

Johnston, Gregory G.

Baird, Michael C.

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Article abstract of DOI:10.1016/0022-328X(86)80382-5

The compound Rh(COMe)(CO)(triphos) appears to react with methyllithium via addition to the acetyl carbon atom to form the complex (CO)(triphos)>(1-), rather than via the expected deprotonation of the acetyl group to form the enolate (ketene) c

Full text of DOI:10.1016/0022-328X(86)80382-5

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Product name:Rh(CO)2(CH₃C(CH₂P(C₆H₅)2)3)^(1-)

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