75187-47-2

Basic information

• Product Name: α,α-diphenylisopropyl acetophenone
• Synonyms: α,α-diphenylisopropyl acetophenone
• CAS NO: 75187-47-2
• Molecular Weight: 314.427
• Mol File: 75187-47-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: α,α-diphenylisopropyl acetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: α,α-diphenylisopropyl acetophenone(75187-47-2)
• EPA Substance Registry System: α,α-diphenylisopropyl acetophenone(75187-47-2)

Safety Data

• Hazardous Substances Data: 75187-47-2(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 525-06-4 diphenyl ketene 
• 17397-37-4 α,α-bromodiphenylacetyl bromide 

Relevant articles and documents

Acylation of aromatic substrates with ketenes. An example of vinyl oxocation reactivity.

Acylations of aromatic substrates with ketenes involve the reactivity of species similar to vinyl cations.Resonance stabilization of ketene-aluminum chloride complexes seems to make these complexes less reactive than corresponding vinyl cations.The kinetic isotope effect of the reaction with dimethylketene and benzene is 1.06, compatible with vinylcation cases, but not with acylation with CH3COBF4 types of electrophiles.Substrate specificity was determined from k (toluene)/k (benzene) values.It was 47.2 for dimethylketene and 173.7 for diphenylketene.The diphenylketene-aluminum chloride complex could be isolated.