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Usage

Uses

Used in Organic Chemistry:
1,1,2,3,4,5-Hexaphenylsilole is used as a reactant in organic synthesis for the formation of bicyclosilaheptene through π4s+π2s cycloaddition with ethyl acrylate. This reaction demonstrates the versatility of HPS in creating complex molecular structures and its potential use in the development of novel compounds.
Used in OLED Emitting Layer:
1,1,2,3,4,5-Hexaphenylsilole is used as an AIE material in the OLED (Organic Light-Emitting Diode) emitting layer for its ability to enhance fluorescence in aggregated states. This property makes it a valuable component in the design and fabrication of OLEDs, contributing to improved device performance and efficiency.
Used in Material Science:
1,1,2,3,4,5-Hexaphenylsilole is used as a component in the development of advanced materials due to its unique aggregation-induced emission properties. Its incorporation into various materials can lead to the creation of novel materials with enhanced optical and electronic properties, applicable in a wide range of industries, including electronics, photonics, and sensing technologies.
Used in Chemical Research:
1,1,2,3,4,5-Hexaphenylsilole is used as a model compound in chemical research to study the behavior of AIE materials and their interactions with other molecules. This research can provide valuable insights into the design and synthesis of new materials with tailored properties for specific applications.

Upstream product

• 501-65-5 diphenyl acetylene 
• 80-10-4 diphenylsilyl dichloride 
• 16030-07-2 1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene 
• 74-88-4 methyl iodide 
• 21289-08-7 1,4-dilithio-1,2,3,4-tetraphenylbutadiene 

Downstream Products

• 1065-76-5 1,4,5,6,7,7-hexaphenyl-7-sila-bicyclo[2.2.1]hept-5-ene-2endo,3endo-dicarboxylic acid anhydride 
• 1762-11-4 1,2,3,4,9,9-hexaphenyl-1,4-dihydro-1,4-episilano-naphthalene 
• 51528-44-0 1,4,5,6,7,7-hexaphenyl-7-sila-bicyclo[2.2.1]hept-5-ene-2endo-carbonitrile 
• 1184-27-6 1,4,5,6,7,7-hexaphenyl-7-sila-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid dimethyl ester 
• 51528-50-8 C,C'-diphenyl-C,C'-(1,4,5,6,7,7-hexaphenyl-7-sila-bicyclo[2.2.1]hepta-2,5-diene-2,3-diyl)-bis-methanone 
• 51528-40-6 1,4,5,6,7,7-hexaphenyl-7-sila-bicyclo[2.2.1]hept-5-ene-2endo-carboxylic acid ethyl ester 
• 752-67-0 1,1,2,3,4,4,5,6-octaphenyl-1,4-dihydro-[1,4]disiline 

Relevant academic research and scientific papers

Reduction of 1-chloro-1,2,3,4,5-pentaphenylsilole: Formation of silole monoanion and dianion

The reduction of 1-chloro-1,2,3,4,5-pentaphenylsilole, (C4Ph4SiPhCl, 1) with 2 equiv lithium gave the pentaphenylsilole anion [C4Ph4SiPh]- (2), silole dianion [C4Ph4Si]2-/s

Electrochemiluminescence Platforms Based on Small Water-Insoluble Organic Molecules for Ultrasensitive Aqueous-Phase Detection

Highly efficient detection in the aqueous phase for water-insoluble organic molecule probes is challenging. The bright aggregated-state electrochemiluminescence (ECL) of 1,1-disubstituted 2,3,4,5-tetraphenylsiloles by a co-reactant approach was discovered

Blue-shifted aggregation-induced emission of siloles by simple structural modification and their application as nitro explosive chemosensors

To induce blue-shifted emission of siloles, two tolyl-substituted derivatives-1,1-diphenyl-2,3,4,5-tetra(m-tolyl)-1H-silole (m-TS) and 1,1-diphenyl-2,3,4,5-tetra(o-tolyl)-1H-silole (o-TS)-were prepared, and their photophysical properties were compared with those of a reference compound, hexaphenylsilole (HPS). By substituting methyl groups at ortho positions of peripheral tetraphenyl rings on the silacyclopentadiene ring, intramolecular rotations could be successfully controlled and the photophysical properties were varied, while substituting methyl groups at meta positions showed similar photophysical properties compared with the case of HPS. That is, simple structural modification at the ortho position significantly affects the geometry and the photophysical properties of silole, which leads to blue-shifted emission. Finally, two tolyl-substituted siloles and HPS were employed as chemosensors for the detection of nitro explosives, and o-TS showed the highest sensing ability.

Enhanced emission efficiency and excited state lifetime due to restricted intramolecular motion in silole aggregates

The aggregation-induced emission (AIE) properties of 1,1,2,3,4,5- hexaphenylsilole (HPS) and poly{11-[(1,2,3,4,5-pentaphenylsilolyl)oxy]-1-phenyl- 1-undecyne} (PS9PA) were studied by time-resolved fluorescence technique. The enhanced fluorescence and long

Efficient blue emission from siloles

2,3,4,5-Tetraphenylsiloles with different 1,1-substituents on the ring silicon atoms, i.e., 1,1-dimethyl-2,3,4,5-tetraphenylsilole (1), 1-methyl-l-(3-chloropropyl)-2,3,4,5-tetraphenylsilole (2), 1-methyl-l,2,3,4,5-pentaphenylsilole (3) and hexaphenylsilol