16030-07-2

Upstream product

• 98-13-5 Phenyltrichlorosilane 
• 501-65-5 diphenyl acetylene 
• 21289-08-7 (E,E)-(1,2,3,4-tetramethyl-1,3-butadien-1,4-ylidene)-dilithium 
• 21289-08-7 1,4-dilithio-1,2,3,4-tetraphenylbutadiene 

Downstream Products

• 16541-42-7 1,2,3,4,5,1',2',3',4',5'-decaphenyl-1H,1'H-1,1'-oxy-bis-silole 
• 18033-79-9 1,1'-bis(1,2,3,4,5-pentaphenyl-1-silacyclopentadien) 
• 4071-98-1 1,2,3,4,5-pentaphenylsilacyclopentadiene 
• 473932-32-0 11-[(1,2,3,4,5-pentaphenylsilolyl)oxy]-1-undecyne 
• 473932-33-1 11-[(1,2,3,4,5-pentaphenylsilolyl)oxy]-1-phenyl-1-undecyne 
• 501423-28-5 1-ethynyl-1,2,3,4,5-pentaphenyl-1H-silole 
• 7641-42-1 1,2,3,4,5-pentaphenyl-1-methylsilole 
• 752-28-3 hexaphenylsilole 
• 7641-40-9 1,1-dimethyl-2,3,4,5-tetraphenylsilole 
• 62795-55-5 tricarbonyl(1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene)ruthenium 
• 62795-58-8 tricarbonyl(1-hydroxy-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene)ruthenium 
• 1130363-03-9 1-(5-Norbornenyl-pentyl)-1,2,3,4,5-pentaphenylsilole 
• 1048682-45-6 1-fluoren-9-yl-1,2,3,4,5-pentaphenylsilole 
• 1048682-44-5 1-(9,9-dimethylfluoren-2-yl)-1,2,3,4,5-pentaphenylsilole 

Relevant academic research and scientific papers

Fluorescent polymeric micelles with aggregation-induced emission properties for monitoring the encapsulation of doxorubicin

A new type of fluorescent polymeric micelles is developed by self-assembly from a series of amphiphilic block copolymers, poly(ethylene glycol)-b-poly[styrene-co-(2-(1,2,3,4,5-pentaphenyl-1H-silol-1-yloxy)ethyl methacrylate)] [PEG-b-P(S-co-PPSEMA)]. Their capability of loading doxorubicin (DOX) is investigated by monitoring the loading content, encapsulation efficiency, and photophysical properties of micelles. F?rster resonance energy transfer from PPSEMA to DOX is observed in DOX-loaded micelles, which can serve as an indication of successful encapsulation of DOX in these micelles. The application of this new type of fluorescent polymeric micelles as a fluorescent probe and an anticancer drug carrier simultaneously is explored by studying the intracellular uptake of DOX-loaded micelles.

Silole derivative, preparation method and application thereof, and lubricating grease

The invention provides a silole derivative, a preparation method and application thereof, and lubricating grease containing the silole derivative. The silole derivative disclosed by the invention hasa structure shown as a formula (I), wherein the definiti

Silole derivative, preparation method and application thereof, and lubricating grease

The invention provides a silole derivative, a preparation method and application thereof, and lubricating grease containing the silole derivative. The silole derivative disclosed by the invention hasa structure shown as a formula (I), wherein the definiti

Luminescent aggregates of a starburst silole-triphenylamine adduct for sensitive explosive detection

A starburst luminogen (THPSTPA) consisting of a triphenylamine core and 1,1,2,3,4,5-hexaphenylsilole peripheries is designed and synthesized. Whereas it is weakly luminescent when molecularly dissolved in good solvent, it becomes highly emissive when aggregated in poor solvent, exhibiting a novel phenomenon of aggregation-induced emission (AIE). THPSTPA is morphologically and thermally stable, showing high glass transition and thermal degradation temperatures at 150 and 303 °C, respectively. The emission of its aggregates can be quenched exponentially by picric acid with a quenching constant up to ～7.0 × 104 L mol-1, suggesting that it can work as a sensitive chemosensor for explosive detection.

SILOLE-BASED MONOMERS AND POLYMERS FOR ORGANIC LIGHT-EMITTING DIODE DEVICES

This invention relates generally to organic electroluminescent norbornene-silole monomers, poly (norbornene) homopolymers, and poly (norbornene) copolymers containing functionalized aryl and alkyl silole side chains having good host characteristics and so

Fluorenyl-substituted silole molecules: Geometric, electronic, optical, and device properties

A series of silole molecules with fluorenyl substituents at varying positions - 1-(9,9-dimethylfluoren-2-yl)-1,2,3,4,5-pentaphenylsilole, 1-(fluoren-9-yl)-1,2,3,4,5-pentaphenylsilole, 1,1,3,4-tetraphenyl-2,5-bis(9,9- dimethylfluoren-2-yl)silole, and 1,1-d

Making silole photovoltaically active by attaching carbazolyl donor groups to the silolyl acceptor core

Appending carbazolyl groups to a hexaphenylsilole core yielded thermally and morphologically stable carbazolylsiloles; the silole carrying two carbazolyl peripheral groups showed photovoltaic activity. The Royal Society of Chemistry 2005.

Silole-containing polyacetylenes. Synthesis, thermal stability, light emission, nanodimensional aggregation, and restricted intramolecular rotation

We synthesized three substituted polyacetylenes carrying 1,2,3,4,5-pentaphenylsilolyl (PS) pendants, i.e., -[HC=C(PS)]n - (1), -{HC=C[(CH2)9OPS]}°n - (2) and -{(C6H5)C=C[(CH2)su