75214-03-8

Basic information

• Product Name: Benzeneacetic acid, a-azido-, ethyl ester
• CAS NO: 75214-03-8
• Molecular Formula: C10H11N3O2
• Molecular Weight: 205.216
• Mol File: 75214-03-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-azido-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-azido-, ethyl ester(75214-03-8)
• EPA Substance Registry System: Benzeneacetic acid, a-azido-, ethyl ester(75214-03-8)

Safety Data

• Hazardous Substances Data: 75214-03-8(Hazardous Substances Data)

Upstream product

• 2882-19-1 ethyl 2-phenyl-2-bromoacetate 
• 22065-57-2 ethyl 2-phenyldiazoacetate 
• 849945-21-7 ethyl 2-phenyl-2-(2-tosylhydrazono)acetate 
• 1603-79-8 phenylglyoxylic acid ethyl ester 
• 1117-96-0 Diazoethan 
• 101-97-3 Ethyl 2-phenylethanoate 

Downstream Products

• 91923-63-6 ethyl 5-oxo-2,4-diphenyl-2,5-dihydro-1H-imidazol-2-carboxylate 
• 6097-58-1 ethyl 2-phenyl-2-aminoacetate 
• 1070671-48-5 ethyl 2-phenyl-2-(4-phenyl-1H-1,2,3-triazol-1-yl)acetate 
• 1027151-90-1 2-(tert-butylamino)-1,4-diphenyl-4,5-dihydro-1H-5-imidazolone 

Relevant articles and documents

Boron-Catalyzed Azide Insertion of α-Aryl α-Diazoesters

A challenging metal-free azide insertion of α-aryl α-diazoesters in the presence of B(C6F5)3 (5 mol %) was developed for the first time. The reaction features an easy operation, wide substrate scope, and mild conditions an

Synthesis ofα-azido ketones and esters using recyclable hypervalent iodine reagent

A simple and mild method for the preparation of αazido ketones and esters using hypervalent iodine reagent, 4,4'-bis-(dichloroiodo)-biphenyl, and sodium azide in 1,4-dioxane is discussed. Advantages of this system are easy workup, recyclable reagent, and

Intermolecular C-H and Si-H insertion reactions with halodiazoacetates

Ethyl halodiazoacetates react with a range of substrates in regioselective rhodium(II)-catalysed C-H and Si-H insertion reactions giving α-halocarbonyl products in up to 82% yield. The halodiazoacetates are a novel class of diazo compounds that can undergo intermolecular carbenoid C-H insertion reactions, thus broadening the synthetic utility of such reactions. Georg Thieme Verlag Stuttgart.