752209-20-4Relevant academic research and scientific papers
PdII- and PtII-mediated polycyclization reactions of 1,5- and 1,6-bienes: Evidence in support of carbocation intermediates
Koh, Jeong Hwan,Gagne, Michel R.
, p. 3459 - 3461 (2004)
Pincer-ligated PdII and PtII dicationic complexes efficiently generate cations from 1,5- and 1,6-dienes. These transient cations can be selectively trapped with heteroatoms, alkenes, and through pinacol rearrangements. For example, trienyl-phenol 1 is converted into tetracyclic 2 in high yield and diastereomeric ratio (see scheme).
