75265-77-9Relevant academic research and scientific papers
Controlling, Understanding, and Redirecting the Thermal Rearrangement of 3,3-Dicyano-1,5-enynes
Scott, Sarah K.,Sanders, Jacob N.,White, Katherine E.,Yu, Roland A.,Houk,Grenning, Alexander J.
supporting information, p. 16134 - 16139 (2018/11/27)
The thermal [3,3] rearrangement of 3,3-dicyano-1,5-enynes to γ-allenyl alkylidenemalononitriles (the "enyne Cope rearrangement") has largely eluded synthetic value as the desired products, too, are thermally reactive and ultimately yield 6π electrocycliza
