75275-66-0

Basic information

• Product Name: ETHYL 3-(BICYCLO[2.2.1]HEPT-5-EN-2-YL)-3-OXOPROPANOATE
• Synonyms: ETHYL 3-(BICYCLO[2.2.1]HEPT-5-EN-2-YL)-3-OXOPROPANOATE
• CAS NO: 75275-66-0
• Molecular Formula: C₁₂H₁₆O₃
• Molecular Weight: 208.25
• Mol File: 75275-66-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL 3-(BICYCLO[2.2.1]HEPT-5-EN-2-YL)-3-OXOPROPANOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 3-(BICYCLO[2.2.1]HEPT-5-EN-2-YL)-3-OXOPROPANOATE(75275-66-0)
• EPA Substance Registry System: ETHYL 3-(BICYCLO[2.2.1]HEPT-5-EN-2-YL)-3-OXOPROPANOATE(75275-66-0)

Safety Data

• Hazardous Substances Data: 75275-66-0(Hazardous Substances Data)

Upstream product

• 141-78-6 ethyl acetate 
• 5063-03-6 2-acetyl-5-norbornene 
• 105-58-8 Diethyl carbonate 

Downstream Products

• 22418-80-0 3-oxopent-4-enoic acid ethyl ester 
• 542-92-7 cyclopenta-1,3-diene 

Relevant articles and documents

A novel biomimetic synthesis of (S)-(-)-zearalenone: Via macrocyclization and transannular aromatization

On heating, a hydroxy-keto-dioxinone underwent retro-Diels-Alder fragmentation and the resultant α,γ-diketo-ketene was efficiently trapped intramolecularly by a secondary alcohol to provide a macrocyclic triketo-lactone. Following ketal hydrolysis, transannular aromatization gave the resorcylate natural product, (S)-(-)-zearalenone.