75277-37-1

Basic information

• Product Name: Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, 4-methylbenzenesulfonate
• CAS NO: 75277-37-1
• Molecular Formula: C17H24O3S
• Molecular Weight: 308.442
• Mol File: 75277-37-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, 4-methylbenzenesulfonate(75277-37-1)
• EPA Substance Registry System: Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, 4-methylbenzenesulfonate(75277-37-1)

Safety Data

• Hazardous Substances Data: 75277-37-1(Hazardous Substances Data)

Upstream product

• 507-70-0 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 24393-70-2 isoborneol 
• 6627-72-1 rac-endo-borneol 

Downstream Products

• 565-00-4 dl-camphene 
• 507-70-0 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol 
• 6627-72-1 rac-endo-borneol 

Relevant articles and documents

Photolyse d' arenesulfonates d' alkyle. Influence des bases et mecanisme de la reaction

Photolysis of alkyl arenesulfonates in various solvents leads to the corresponding alkyl alcohols in good chemical yields.Aromatic hydrocarbons and sulfur dioxide are also characterized in the reaction mixture.In the first step, homolysis of the C-S bond takes place from the sulfonate excited in a singlet state.In basic medium the reaction becomes cleaner and more efficient.Thr quenching of the fluorescence by NaOH, with 3 β-cholestanyl p-toluenesulfonate, seems to be diffusioncontrolled.The role of the base is discussed.