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High purity Borneol
Cas No: 507-70-0
No Data 1 Kilogram 1500 Kilogram/Year Siwei Development Group Ltd. Contact Supplier
Borneol
Cas No: 507-70-0
USD $ 2.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Year Antimex Chemical Limied Contact Supplier
Borneol in stock
Cas No: 507-70-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High purity Borneol CAS:507-70-0
Cas No: 507-70-0
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Natural borneol
Cas No: 507-70-0
USD $ 2.0-2.0 / Kilogram 1 Kilogram 100 Metric Ton/Year Hebei yanxi chemical co.,LTD. Contact Supplier
Natural Borneol Cas 507-70-0 with high purity and best price
Cas No: 507-70-0
USD $ 380.0-388.0 / Kilogram 1 Kilogram 8 Metric Ton/Year Wuhan Fortuna Chemical Co.,Ltd Contact Supplier
Natural borneol
Cas No: 507-70-0
No Data 25 Kilogram 1500 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
Borneol
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No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Factory Supply DL-borneol
Cas No: 507-70-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
Amadis Chemical offer CAS#507-70-0;CAT#A828291
Cas No: 507-70-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier

507-70-0 Usage

Fire Hazard

Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.

References

[1] N. Zhang, P. Liu and X. He, Effect of borneol, moschus, storax, and acorus tatarinowii on expression levels of four amino acid neurotransmitters in the rat corpus striatum, Neural Regen Res., 2012, vol. 7, 440-444 [2] George A. Burdock, Encyclopedia of Food and Color Additives, Volume 1, 2000

General Description

A white colored lump-solid with a sharp camphor-like odor. Burns readily. Slightly denser than water and insoluble in water. Used to make perfumes.

Aroma threshold values

Detection: 140 ppb

Chemical Properties

Borneol has a piney, camphor-like odor and burning taste somewhat reminiscent of mint.

Air & Water Reactions

Flammable. Insoluble in water.

Definition

ChEBI: A bornane monoterpenoid that is 1,7,7-trimethylbicyclo[2.2.1]heptane substituted by a hydroxy group at position 2.

Description

Borneol, also called “compound long nao,” is a colorless and transparent crystal, which has a pungent, camphor-like odor and a burning taste reminiscent of mint. It occurs naturally in cinnamon leaf, ginger, Thymus, cardamom, coriander leaf, coriander seed, etc. Borneol has been shown to enhance blood-brain barrier (BBB) permeability and increase brain concentrations of drugs, as well as protect the brain and BBB while inducing no pathological damage. Thus, borneol is used as a promoter of drug absorption. Borneol is also used as a food additive permitted for direct addition to food for human consumption.

Reactivity Profile

Borneol is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

Chemical Properties

solid

Health Hazard

Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Occurrence

Unlike isoborneol, free or esterified borneol has been identified in more than 250 distillates from plants, herbs, leaves or bark; Compositae, Ericaceae, Lauraceae, Labiatea, Rutaceae; natural borneol can be d or l rotatory, but very seldom also racemic; most frequently encountered is the l-borneol characteristic of Compositae, Graminaceae and almost all Pinaceae; d-borneol characteristic of Cupressaceae, Zingiberaceae, lavender, lavandin and spike oils. Reported found in citrus peel oils (orange, lemon, lime), cinnamon leaf, cassia leaf, ginger, coriander seed, laurel, Ocimum basilicum, Thymus vulgaris L. and Curcuma aeruginosa Roxb.

Chemical Synthesis

Racemic borneol is prepared synthetically by reduction of camphor or from pinene.

Uses

Perfumery, esters.

Chemical Properties

Borneol is a bicyclic terpene alcohol. Borneol is an endo isomer; the corresponding exo isomer is isoborneol: Borneol occurs abundantly in nature as a single enantiomer or, less frequently, as the racemate. (1S,2R,4S)-(?)-Borneol occurs particularly in oils from Pinaceae species and in citronella oil. (1R,2S,4R)-(+)-Borneol is found, for example, in camphor oil (Ho-Sho oil), rosemary, lavender, and olibanum oils. Borneol is a colorless, crystalline solid. (+)-Borneol has a camphoraceous odor, with a slightly sharp, earthy, peppery note, which is less evident in (?)-borneol. Commercial borneol is often levorotatory ([α]20 D ?18 to ?28 in ethanol) and contains (?)-borneol and up to 40% isoborneol. Borneol is oxidized to camphor with chromic or nitric acid; dehydration with dilute acids yields camphene. Borneol is readily esterified with acids, but on an industrial scale, bornyl esters are prepared by other routes. For example, levorotatory borneol is synthesized industrially from levorotatory pinenes by Wagner–Meerwein rearrangement with dilute acid, followed by hydrolysis of the resulting esters. Borneol is used in the reconstitution of the essential oils in which it occurs naturally.

Hazard

Fire risk in presence of open flame.
InChI:InChI=1/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h6-7,11H,4-5H2,1-3H3

507-70-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (B0525)  Borneol (contains ca. 20% Isoborneol)  >70.0%(GC) 507-70-0 25g 195.00CNY Detail
TCI America (B0525)  Borneol (contains ca. 20% Isoborneol)  >70.0%(GC) 507-70-0 500g 950.00CNY Detail

507-70-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name borneol

1.2 Other means of identification

Product number -
Other names methyl isobornyl ether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:507-70-0 SDS

507-70-0Synthetic route

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one
736109-58-3, 787517-91-3

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With sodium tetrahydroborate; water; titanium(IV) oxide at 20℃; for 1h; regioselective reaction;98%
With hydrogenchloride; K9-OThx-9-BBNH) In tetrahydrofuran at 0℃; Product distribution; stereoselectivity, other boranes;97.5%
With Triethoxysilane; cesium fluoride at 25℃; for 0.0166667h;95%
2-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

2-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With silica triflate In methanol for 0.333333h; Heating;93%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With silica triflate In methanol for 0.0666667h; Heating;90%
With methanol at 20℃; for 0.916667h;89%
With ammonium chloride In water; acetonitrile at 80℃; for 1.5h;83%
Adipic acid
124-04-9

Adipic acid

1-methylcamphene
13144-43-9

1-methylcamphene

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With iron(III) perchlorate for 3h; Ambient temperature;85%
dichloromethane
75-09-2

dichloromethane

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one
736109-58-3, 787517-91-3

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

A

2-methylenebornane
27538-47-2

2-methylenebornane

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With titanium tetrachloride; magnesium In tetrahydrofuran at 0 - 20℃; for 1h;A 74%
B n/a
ethanol
64-17-5

ethanol

toluene-4-sulfonic acid isobornyl ester
20053-48-9, 22467-56-7, 22467-57-8, 75277-37-1

toluene-4-sulfonic acid isobornyl ester

sodium ethanolate
141-52-6

sodium ethanolate

dl-camphene
565-00-4

dl-camphene

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one
736109-58-3, 787517-91-3

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

A

d-borneol
464-43-7

d-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With acetic acid; platinum Hydrogenation;
With copper at 120 - 150℃; under 7600 - 69920 Torr; Hydrogenation;
exo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol formate
74219-20-8, 100101-30-2

exo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol formate

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
beim Verseifen; formic acid isobornyl ester;
4-chloro-2-isopropyl-5-methyl-benzenesulfonic acid isobornyl ester

4-chloro-2-isopropyl-5-methyl-benzenesulfonic acid isobornyl ester

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

dl-camphene
565-00-4

dl-camphene

C

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 50℃;
Camphor
76-22-2

Camphor

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
With hydrogen; nickel
With alcoholic alkali
With alkali metal
With hydrogen; copper
With diethyl ether; sodium Zersetzen des Reaktionsprodukts durch Wasser;
rac O-isoborneol S-methyl carbonodithioate
37487-17-5, 70061-64-2, 79646-02-9, 108691-64-1

rac O-isoborneol S-methyl carbonodithioate

dl-camphene
565-00-4

dl-camphene

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 140 - 175℃;
oxalic acid dibornyl ester
105660-96-6

oxalic acid dibornyl ester

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
oxalic acid di-dl-isobornyl ester;
4-chloro-2-isopropyl-5-methyl-benzenesulfonic acid bornyl ester
1071684-68-8

4-chloro-2-isopropyl-5-methyl-benzenesulfonic acid bornyl ester

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

dl-camphene
565-00-4

dl-camphene

C

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Beta-pinene
177698-19-0

Beta-pinene

2,3,4-trichlorophenol
15950-66-0

2,3,4-trichlorophenol

A

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

B

fenchyl ether

fenchyl ether

C

l-α-pinene

l-α-pinene

Conditions
ConditionsYield
at 145 - 150℃; levorotatory form;
camphene
79-92-5

camphene

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
im geschlossenen Gefaess; dl-camphene;
camphene
79-92-5

camphene

o-toluenesulfonic acid
88-20-0

o-toluenesulfonic acid

water
7732-18-5

water

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 20℃;
hydrogenchloride
7647-01-0

hydrogenchloride

camphene
79-92-5

camphene

acetone
67-64-1

acetone

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
im geschlossenen Gefaess; dl-camphene;
camphene
79-92-5

camphene

sulfuric acid
7664-93-9

sulfuric acid

acetone
67-64-1

acetone

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
im geschlossenen Gefaess; dl-camphene;
camphene
79-92-5

camphene

sulfonic acid

sulfonic acid

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
im geschlossenen Gefaess; dl-camphene;
acetic acid
64-19-7

acetic acid

boronacetic acid anhydride

boronacetic acid anhydride

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
folgend Verseifen; dl-α-pinene;
carboxylic acid anhydride

carboxylic acid anhydride

boric acid anhydride

boric acid anhydride

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
dl-α-pinene;
carboxylic acid

carboxylic acid

boric acid anhydride

boric acid anhydride

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
dl-α-pinene;
diethyl ether
60-29-7

diethyl ether

(1R,2S,4R)-2-Chloro-1,7,7-trimethyl-bicyclo[2.2.1]heptane
30462-53-4

(1R,2S,4R)-2-Chloro-1,7,7-trimethyl-bicyclo[2.2.1]heptane

oxygen

oxygen

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
bei der Einwirkung auf die Grignard-Verbindung;
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
464-49-3

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

hydrogen

hydrogen

cobalt

cobalt

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
464-49-3

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

hydrogen

hydrogen

copper

copper

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

ethanol
64-17-5

ethanol

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
464-49-3

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

KOH

KOH

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 180 - 200℃;
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
464-49-3

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

hydrogen

hydrogen

nickel

nickel

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

ethanol
64-17-5

ethanol

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
464-49-3

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

sodium

sodium

rac-endo-borneol
6627-72-1

rac-endo-borneol

B

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 200 - 220℃;
(+)-α-pinene
7785-70-8

(+)-α-pinene

acetic acid
64-19-7

acetic acid

fired clay

fired clay

A

terpineol
98-55-5

terpineol

B

D-limonene
5989-27-5

D-limonene

rac-endo-borneol
6627-72-1

rac-endo-borneol

D

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 30℃; anschl. Verseifen;
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one
736109-58-3, 787517-91-3

1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

Conditions
ConditionsYield
With acetone; zirconic acid In benzene at 80℃; for 8h; Rate constant;100%
With acetone; zirconic acid In benzene at 80℃; for 8h;100%
With silica gel; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate In dichloromethane100%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

camphene
79-92-5

camphene

Conditions
ConditionsYield
molybdophosphoric acid; silica gel In chloroform for 0.5h; Heating;99%
With bis(2,2,2-trifluoroethoxy)triphenylphosphorane61%
With sulfuric acid; water dl-camphene;
Conditions
ConditionsYield
With lithium perchlorate at 25℃; for 6h;98%
samarium(III) trifluoromethanesulfonate at 20℃; for 0.25h;96%
With iron(III) p-toluenesulfonate hexahydrate In acetonitrile at 50℃; for 30h;92%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

1,7,7-trimethyltricyclo[2.2.1.02,6]heptane
508-32-7

1,7,7-trimethyltricyclo[2.2.1.02,6]heptane

Conditions
ConditionsYield
molybdophosphoric acid; silica gel In chloroform for 2h; Heating;98%
Conditions
ConditionsYield
With P(MeNCH2CH2)3N In tetrahydrofuran at 50℃; for 16h;96%
trimethylsilylazide
4648-54-8

trimethylsilylazide

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
tetrabutylammomium bromide at 30℃; for 0.166667h;96%
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

2-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

2-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

Conditions
ConditionsYield
With silica triflate In hexane at 20℃; for 0.316667h;95%
With iodine In tetrahydrofuran for 0.1h; microwave irradiation;78%
copper bis(ethyl-3-hydroxy-4,4,4-trifluoro-2-butenoate)

copper bis(ethyl-3-hydroxy-4,4,4-trifluoro-2-butenoate)

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

bis(bornyl-4,4,4-trifluoro-3-oxobutanoato)copper(II)

bis(bornyl-4,4,4-trifluoro-3-oxobutanoato)copper(II)

Conditions
ConditionsYield
In octane heated for 40 h; cooled, washed (water), residue filtered, precipiated from acetone withwater; elem. anal.;95%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

A

propene
187737-37-7

propene

B

Borneol, trimethylsilyl ether
74472-21-2, 37555-29-6, 37555-30-9, 88390-69-6

Borneol, trimethylsilyl ether

Conditions
ConditionsYield
iodine In chloroform at 60℃; for 1h;A n/a
B 94%
Cu[OC(C4F9)CHC(COOC2H5)O]2

Cu[OC(C4F9)CHC(COOC2H5)O]2

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

bis(bornyl-5,5,6,6,7,7,8,8,8-nonafluoro-2,4-dioxopentanoato)copper(II)

bis(bornyl-5,5,6,6,7,7,8,8,8-nonafluoro-2,4-dioxopentanoato)copper(II)

Conditions
ConditionsYield
In octane boiled for 4 h; cooled, washed (water), evapd., precipitated from CHCl3 with hexane; elem. anal.;94%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole
57680-64-5

8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

{Rh(CO)Cl(P(OC6(CH3)C(CH3)2H8)(OC2H4)2NH)}
153006-19-0

{Rh(CO)Cl(P(OC6(CH3)C(CH3)2H8)(OC2H4)2NH)}

Conditions
ConditionsYield
In dichloromethane (under Ar) bornil in CH2Cl2 is added dropwise with stirring to a soln. of BAP in CH2Cl2, the soln. is stirred for 1 h and then is added (Rh(CO)2Cl)2 in CH2Cl2; ppt. is separated, washed with ether and pentane and dried in air in vac. (1mm Hg), elem. anal.;93%
Cu[OC(CH3)CHC(COOCH3)O]2

Cu[OC(CH3)CHC(COOCH3)O]2

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

bis(bornyl-2,4-dioxopentanoato)copper(II)

bis(bornyl-2,4-dioxopentanoato)copper(II)

Conditions
ConditionsYield
In octane boiled for 4 h; cooled, washed (water), evapd., precipitated from CHCl3 with hexane; elem. anal.;93%
bis(ethyl acetoacetato)copper(II)

bis(ethyl acetoacetato)copper(II)

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

bis(bornyl-3-oxobutanoato)copper(II)

bis(bornyl-3-oxobutanoato)copper(II)

Conditions
ConditionsYield
In octane heated for 40 h; cooled, washed (water), residue filtered, precipiated from acetone withwater; elem. anal.;93%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Conditions
ConditionsYield
With sulfuric acid In dichloromethane at 20℃; for 9h;92%
With 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0833333h; Neat (no solvent);90%
In acetonitrile at 20℃; for 0.916667h;90%
With copper(II) nitrate trihydrate at 20℃; for 5h; Neat (no solvent);50%
dimethyltitanocene
1271-66-5

dimethyltitanocene

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

(C5H5)2Ti(CH3)(C10H17O)

(C5H5)2Ti(CH3)(C10H17O)

Conditions
ConditionsYield
In hexane byproducts: CH4; (Ar), heated under reflux for 48 h; solvent removed in vac., recrystd., chromy.( Al2O3, hexane- ether 5:1 ); NMR;92%
Cu[OC(CF3)CHC(COOCH3)O]2

Cu[OC(CF3)CHC(COOCH3)O]2

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

bis(bornyl-5,5,5-trifluoro-2,4-dioxopentanoato)copper(II)

bis(bornyl-5,5,5-trifluoro-2,4-dioxopentanoato)copper(II)

Conditions
ConditionsYield
In octane boiled for 4 h; cooled, washed (water), evapd., precipitated from CHCl3 with hexane; elem. anal.;92%
Dimethoxymethane
109-87-5

Dimethoxymethane

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

C12H22O2
127938-47-0

C12H22O2

Conditions
ConditionsYield
With benzyltriphenylphosphonium tribromide In chloroform for 0.916667h; Reflux;92%
With melamine-N2,N4,N6-trisulfonic acid In chloroform for 1h; Reflux;80%
(S)-tetrahydro-1,4-epoxynaphthalene-1-carboxylic acid chloride

(S)-tetrahydro-1,4-epoxynaphthalene-1-carboxylic acid chloride

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

(1S,4R)-borneyl 1,2,3,4-tetrahydro-1,4-epoxynaphthalene-1-carboxylate

(1S,4R)-borneyl 1,2,3,4-tetrahydro-1,4-epoxynaphthalene-1-carboxylate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 20℃; for 8h; Inert atmosphere;91%
malonic acid
141-82-2

malonic acid

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Malonic acid bis-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl) ester
877133-47-6, 75863-06-8

Malonic acid bis-(1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl) ester

Conditions
ConditionsYield
With diphenylammonium trifluoromethanesulfonate In toluene at 80℃; for 22h;90.8%
bromobenzene
108-86-1

bromobenzene

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

C16H21Br

C16H21Br

Conditions
ConditionsYield
Stage #1: bromobenzene; 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol With hydrogenchloride for 0.333333h;
Stage #2: With sulfuric acid at 125℃; for 6h;
90%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

C22H25Br

C22H25Br

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl; 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol With hydrogenchloride for 0.333333h;
Stage #2: With sulfuric acid at 120℃; for 4h; Temperature;
90%
2-bromo-3,4,4-trichloro-3-butenoyl chloride
913966-90-2

2-bromo-3,4,4-trichloro-3-butenoyl chloride

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

isoborneolyl 2-bromo-3,4,4-trichlorobut-3-enoate

isoborneolyl 2-bromo-3,4,4-trichlorobut-3-enoate

Conditions
ConditionsYield
With pyridine In benzene at 20 - 23℃;89%
With pyridine In benzene at 20 - 23℃;87%
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

1,3,5-Tris-((1S,2R,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-[1,3,5]triazinane-2,4,6-trione

1,3,5-Tris-((1S,2R,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-[1,3,5]triazinane-2,4,6-trione

Conditions
ConditionsYield
With sodium hydride88%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

3,3,4,4,4-pentachlorobutanoic acid chloride
484067-67-6

3,3,4,4,4-pentachlorobutanoic acid chloride

(Z)-3,4,4,4-Tetrachloro-but-2-enoic acid (1S,2R,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

(Z)-3,4,4,4-Tetrachloro-but-2-enoic acid (1S,2R,4S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Conditions
ConditionsYield
With pyridine In diethyl ether at 20 - 23℃;88%
With pyridine In diethyl ether at 20 - 23℃;86%
Conditions
ConditionsYield
With 2,2'-(phenylimino)bis[ethanol]; diethylzinc In hexane; toluene at 20℃; for 24h;86%
1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

(1R,3S)-2,2-dimethyl-3-(1,3-dithian-2-yl)cyclopropanecarboxylic acid
194718-39-3

(1R,3S)-2,2-dimethyl-3-(1,3-dithian-2-yl)cyclopropanecarboxylic acid

(1R,3S)-3-[1,3]Dithian-2-yl-2,2-dimethyl-cyclopropanecarboxylic acid 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

(1R,3S)-3-[1,3]Dithian-2-yl-2,2-dimethyl-cyclopropanecarboxylic acid 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane Ambient temperature;85%

507-70-0Upstream product

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