75288-48-1

Basic information

• Product Name: Benzene, 1-bromo-2-[(2-chloro-2-propenyl)thio]-
• CAS NO: 75288-48-1
• Molecular Formula: C9H8BrClS
• Molecular Weight: 263.586
• Mol File: 75288-48-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-2-[(2-chloro-2-propenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-2-[(2-chloro-2-propenyl)thio]-(75288-48-1)
• EPA Substance Registry System: Benzene, 1-bromo-2-[(2-chloro-2-propenyl)thio]-(75288-48-1)

Safety Data

• Hazardous Substances Data: 75288-48-1(Hazardous Substances Data)

Upstream product

• 78-88-6 2,3-Dichloroprop-1-ene 
• 6320-02-1 o-bromothiophenol 

Downstream Products

• 75288-53-8 2-methyl-7-(3-p-toluenesulphonylpropyl)benzothiophen 
• 75288-52-7 2-methyl-7-(2-p-toluenesulphonylethyl)benzothiophen 
• 75288-49-2 7-bromo-2-methylbenzothiophen 

Relevant articles and documents

The Synthesis of Thiophenium and Oxazolium Salts from Diazoketones

4-Diazoacetylthianthren with perchloric acid in acetonitrile gave 2-oxo-1,2-dihydrothieno-thianthrenium perchlorate which gave the corresponding enol ether with diazomethane.This ether was compared with 3-methoxy-1-methylbenzothiophenium perchlorate, prepared from 3-methoxythiophen, and which was much more stable to solvolysis than the demethoxy-analogue.In contrast to the 4-diazoacetylthianthren, 7-diazoacetyl-2-methylbenzothiophen with acetonitrile and perchloric acid cyclized in an alternative mode to give a new synthesis of 2-methyl-4-substituted oxazolium perchlorates.