75336-69-5Relevant academic research and scientific papers
Stereodirecting effect of the pyranosyl C-5 substituent in glycosylation reactions
Dinkelaar, Jasper,De Jong, Ana Rae,Van Meer, Robert,Somers, Mark,Lodder, Gerrit,Overkleeft, Herman S.,Codee, Jeroen D. C.,Van Der Marel, Gijsbert A.
experimental part, p. 4982 - 4991 (2009/10/09)
(Chemical Equation Presented) The stereodirecting effect of the glycosyl C-5 substituent has been investigated in a series of D-pyranosyl thioglycoside donors and related to their preferred positions in the intermediate 3H4 and
An extremely mild and stereocontrolled construction of 1,2-trans-β-glycosidic linkages capitalizing on benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors
Hashimoto, Shun-Ichi,Umeo, Kazuhiro,Sano, Ai,Watanabe, Nobuhide,Nakajima, Makoto,Ikegami, Shiro
, p. 2251 - 2254 (2007/10/02)
A highly stereocotrolled 1,2-trans-β-glycosidation reaction without neighboring group participation has been developed by using benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors and boron trifluoride etherate as a promoter. The present
A Rapid and Efficient Synthesis of 1,2-trans-β-Linked Glycosides via Benzyl- or Benzoyl-protected Glycopyranosyl Phosphates
Hashimoto, Shun-ichi,Honda, Takeshi,Ikegami, Shiro
, p. 685 - 687 (2007/10/02)
A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl t
Stereoselective glycosidations of uronic acids
Schmidt, Richard R.,Ruecker, Ernst
, p. 1421 - 1424 (2007/10/02)
Stereoselective glycosidation and disaccharide formation of uronic acids were performed with silver perchlorate in acetonitrile. The course of the reaction is controlled by intermediate nitrilium acetonitrile conjugates, which are generated in situ.
