75336-64-0

Upstream product

• 75336-65-1 methyl 2,3,4-tri-O-benzyl-α-D-glucopyranuronate 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Downstream Products

• 55610-74-7 (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 55610-71-4 methyl (methyl-2,3,4-tri-O-benzyl-α-D-glucopyranosid)uronate 
• 75336-69-5 (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 75336-67-3 (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 75336-66-2 (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-((2R,3R,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-furan-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 75336-68-4 (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-((3aR,6R,7S,7aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective glycosidations of uronic acids

Stereoselective glycosidation and disaccharide formation of uronic acids were performed with silver perchlorate in acetonitrile. The course of the reaction is controlled by intermediate nitrilium acetonitrile conjugates, which are generated in situ.