75337-07-4Relevant academic research and scientific papers
The Stabilities of Meisenheimer Complexes. Part 20. Kinetic and Equilibrium Data for the Reactions of Some Aromatic Nitro Compounds with Propoxide Ions in Propan-1-ol.
AlAruri, Ahmad D. A.,Crampton, Michael R.
, p. 2157 - 2184 (2007/10/02)
Rate and equilibrium data are reported for the formation of ?-adducts by the reaction of propoxide ions in propan-1-ol with 1,3,5-trinitrobenzene and a series of 1-propoxy-2,4-dinitro-6-X-benzenes (X = NO2, Cl, CO2Pr, H).The results are compared with those for ethoxide and isopropoxide additions.There is evidence for strong association with sodium ions of the 1,1-dipropoxy adducts; but adducts formed by base addition at unsubstituted positions are not strongly associated.In the nucleophilic substitution reaction with 1-chloro-2,4-dinitrobenzene free propoxide ions show greater reactivity than sodium propoxide ion-pairs.
