75340-13-5Relevant academic research and scientific papers
PHENYLTHIOMETHYLTRIMETHYLSILANE: A NEW FORMYL ANION SYNTHON
Kocienski, Philiph J.
, p. 1559 - 1562 (2007/10/02)
α-Phenylthioalkyltrimethylsilanes, readily prepared by the alkylation of phenylthiomethyltrimethylsilane with alkyl halides or epoxides, can be converted to O-trimethylsilyl hemithioacetals via a Sila-Pummerer Rearrangement of the corresponding sulfoxides.The O-trimethylsilyl hemithioacetals are readily hydrolyzed to aldehydes.
