753459-20-0Relevant academic research and scientific papers
The exclusivity of multivalency in dynamic covalent processes
Badjic, Jovica D.,Cantrill, Stuart J.,Grubbs, Robert H.,Guidry, Erin N.,Orenes, Raul,Stoddart, J. Fraser
, p. 3273 - 3278 (2004)
Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as
Synthesis of small and large fused bicyclic compounds by tandem dienyne ring-closing metathesis
Park, Hyeon,Hong, You-Lee,Kim, Yongjoo B.,Choi, Tae-Lim
supporting information; experimental part, p. 3442 - 3445 (2010/10/01)
(Equation Presented). A tandem ring-closing metathesis reaction using ruthenium catalyst was carried out to synthesize various fused bicyclic compounds containing both small and large rings. Fast ring-closure of the small ring and slow ring-closure of the large ring resulted in the formation of only one isomer. Further manipulation such as the Diels-Alder reaction was carried out to prepare a complex molecule containing multiple rings of different sizes.
