75359-62-5Relevant academic research and scientific papers
New methodology for conjugate additions of allylic ligands to α,β-unsaturated ketones: Synthetic and spectroscopic studies
Lipshutz, Bruce H.,Ellsworth, Edmund L.,Dimock, Stuart H.,Smith, Robin A.J.
, p. 4404 - 4410 (2007/10/02)
Michael additions of allylic ligands, including allyl, methallyl, crotyl, and prenyl systems, to a variety of α,β-unsaturated ketones can be effected in synthetically useful yields with allylcopper reagents in the presence of trimethylchlorosilane. Low-te
LATENT ACETONYLATION OF α,β-ENONES WITH ALLYLTRIMETHYLSILANE OR 2-METHYL-2-PROPENYLTRIMETHYLSILANE: SYNTHESIS OF 1,5-DIKETONES AND ANNELATION TO FUSED CYCLOHEXENONES
Hosomi, Akira,Kobayashi, Hiroshi,Sakurai, Hideki
, p. 955 - 958 (2007/10/02)
Acetonylation of α,β-enones can be achieved by either with (2-methyl-2-propenyl)trimethylsilane or with allyltrimethylsilane followed by oxidative cleavage of the double bond or by the Wacker reaction, respectively.Annelation of the 1,5-diketones is also
