754-43-8Relevant academic research and scientific papers
Some new chemistry of perfluoro-t-butylsilver
Rossman, David E.,Muller, August J.,Lewis, Everett O.
, p. 221 - 224 (1991)
Perfluoro-t-butylsilver, prepared by the reaction of silver fluoride with perfluoroisobutene, has been used to prepare new perfluoro-t-butyl derivatives in good yield.
Pyrolysis of branched-chain perfluoroalkanes in the presence of halogens
Tonelli, Claudio,Tortelli, Vito
, p. 125 - 128 (2007/10/03)
The thermal decomposition of some highly branched perfluoroalkanes in the presence of molecular halogens (Cl2, Br2, I2) has been studied.The clear-cut cleavage of the most hindered carbon-carbon bond and the trapping by halogens of the intermediate radicals so formed account for the product distribution.Kinetic measurements support a mechanism based on homolytic rupture of the perfluoroalkanes as the rate-determining step, followed by the fast reaction of the intermediates with halogens.
REACTIONS INVOLVING FLUORIDE ION. PART 34. STABLE PERFLUORINATED CARBANIONS
Bayliff, Andrew E.,Chambers, Richard D.
, p. 201 - 208 (2007/10/02)
A remarkable series of perfluoroalkyl anions, generated by reaction of caesium fluoride with various perfluorinated alkenes have been observed by (19)F and (13)C n.m.r. spectroscopy.Trapping experiments are described and threshold temperatures are established for the onset of fluoride ion exchange.The effects of counter ions are compared and (Me2N)3S+ (TAS) salts are more readily produced than Cs+ salts, but exchange of fluoride ion with fluorinated alkenes occurs more readily with TAS salts.Ph4P+ and Bu4N+ salts could not be obtained.Competition experiments for CsF between various perfluoroalkenes has established orders of carbanion stability.
Tris(disubstituted amino)sulfonium perfluorocarbanion salts
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, (2008/06/13)
Tris(disubstituted amino)sulfonium perfluorocarbanion salts and process for their preparation.
Direct Observation of Simple Fluorinated Carbanions
Bayliff, Andrew E.,Bryce, Martin R.,Chambers, Richard D.,Matthews, Raymond S.
, p. 1018 - 1019 (2007/10/02)
Simple perfluorinated carbanions are generated and observed by (19)F and (13)C n.m.r. spectroscopy; curious low-field shifts are observed for sites adjacent to the charged centres.
