382-24-1

Basic information

• Product Name: 1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE
• Synonyms: Tris(trifluoromethyl)methane;1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propane 97%;1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propane97%;2-trifluoromethyl-1,1,1,3,3,3-hexafluoropropane;Isobutane, perfluoro-;Propane, 1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-;1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE
• CAS NO: 382-24-1
• Molecular Formula: C₄HF₉
• Molecular Weight: 220.04
• Mol File: 382-24-1.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 12-14°C
• Appearance: /
• Density: 1.526g/cm³
• Vapor Pressure: 1100mmHg at 25°C
• Refractive Index: 1.24
• PKA: 11(at 25℃)
• CAS DataBase Reference: 1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE(382-24-1)
• EPA Substance Registry System: 1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE(382-24-1)

Safety Data

• Hazard Codes: T
• Statements: 23/24/25
• Safety Statements: 36/37/39-45
• Hazardous Substances Data: 382-24-1(Hazardous Substances Data)

Usage

General Description

1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propane is a fluorinated hydrocarbon compound with the chemical formula C4F6. It is a colorless, odorless gas at room temperature and pressure. 1,1,1,3,3,3-HEXAFLUORO-2-(TRIFLUOROMETHYL)PROPANE is primarily used as a refrigerant in air conditioning and refrigeration systems, as well as a blowing agent in the production of foam insulation and packaging materials. It is also used as a solvent in the semiconductor industry and as a propellant in aerosol products. Due to its low toxicity and flammability, as well as its ozone-depleting potential, 1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propane is considered a preferable alternative to other fluorinated compounds in various industrial applications.

InChI:InChI=1/C4HF9/c5-2(6,7)1(3(8,9)10)4(11,12)13/h1H

Upstream product

• 382-21-8 perfluoroisobutylene 
• 13027-23-1 3,3,3-trifluoro-2,2-bis-trifluoromethyl-propionyl chloride 
• 34880-30-3 bis(nonafluoro-tert-butyl) disulfide 
• 7380-81-6 ethyl (dimethylsulfuranylidene)acetate 
• 77-99-6 1,1,1-tri(hydroxymethyl)propane 
• 64-17-5 ethanol 
• 104823-35-0 C₈F₁₆NO^(1-)*Cs⁽¹⁺⁾ 
• 85093-54-5 N-(1-Ethoxy-2,2,2-trifluoro-1-trifluoromethyl-ethyl)-3,3,3-trifluoro-2,2-bis-trifluoromethyl-propionamide 
• 107-21-1 ethylene glycol 
• 96-24-2 3-monochloro-1,2-propanediol 
• 56-81-5 glycerol 
• 354-92-7 perfluoroisobutylene 
• 75-05-8 acetonitrile 
• 653-34-9 2,3,4,5,6-pentafluorostyrene 

Downstream Products

• 6248-34-6 5,5,5-trifluoro-4,4-bis-trifluoromethyl-pentanal 
• 115-10-6 Dimethyl ether 
• 62498-14-0 trans-1,3-bis(perfluoro-tert-butyl)propene 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 
• 7789-21-1 fluorosulphonic acid 
• 68596-32-7 Phenylperfluor-tert.-butylsulfid 
• 18448-19-6 2,2-bis-trifluoromethyl-pent-4-enoic acid allyl ester 
• 69162-13-6 N,N-Dimethyl-S-(2,2,2-trifluoro-1,1-bis-trifluoromethyl-ethyl)-thiohydroxylamine 
• 4459-16-9 2-chlorononafluoro-2-methylpropane 
• 105752-96-3 2,2-dichlorotrifluoroethyl-3,3-bis(trifluoromethyl)-4,4,4-trifluorobutyl sulfone 
• 17078-50-1 (Z)-2-(2,2,2-Trifluoro-1,1-bis-trifluoromethyl-ethyl)-but-2-enedioic acid dimethyl ester 
• 17078-49-8 1-(Perfluor-tert.-butyl)-2-benzoyl-ethylen 
• 10568-99-7 5,5,5-Trifluoro-4,4-bis-trifluoromethyl-pentanoic acid methyl ester 
• 5634-47-9 5,5,5-Trifluor-4,4-bis-trifluormethyl-valeronitril 

Relevant articles and documents

CONDENSATION OF PERFLUOROISOBUTYLENE WITH ACETONITRILE

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The reactivities of perfluoroisopropyl and tert-butyl radicals towards hydrogen atom abstraction from triethylsilane

The rates of hydrogen abstraction from triethylsilane by the highly electrophilic perfluoroisopropyl and perfluoro-tert-butyl radicals have been obtained through competition experiments. These rates, 3.6 × 106 and 2.4 × 108 M-1 s-1, respectively, are indicative of substantial reactivity enhancements, relative to perfluoro-n-alkyl radicals, derived from their enhanced electrophilicity and, in the latter case, from a much stronger forming C-H bond.

Novel reactions of perfluoro-2-(trifluoromethyl)-propene

Unlike its hydrocarbon counterpart, perfluoro-2-(trifluoromethyl)propene is a highly reactive compound.It participates in both heterolytic and homolytic reactions.It readily reacts with nucleophiles and sluggishly with electrophiles.It reacts as well with common organic solvents, such as dimethylformamide, ethanol and others.In this communication we describe its reactions with trifluoromethylthiocopper, sulfur trioxide and tributyltin cyanide, the mechanism of formation of the various products and their mass spectral data.

FLUORINE-CONTAINING IMINES. COMMUNICATION 6. REACTION OF HEXAFLUOROACETONE PERFLUOROPIVALOYLIMINE WITH DIMETHYLANILINE AND DIMETHYLBENZYLAMINE

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