75413-34-2Relevant academic research and scientific papers
Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones
Zhao, Liang,Wang, Jinlian,Zheng, Hongyan,Li, Yun,Yang, Ke,Cheng, Bin,Jin, Xiaojie,Yao, Xiaojun,Zhai, Hongbin
supporting information, p. 6378 - 6381 (2015/01/09)
A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.
ORGANOMETALLIC COMPOUNDS IN ORGANIC SYNTHESIS-PART 17; REACTIONS OF TRICARBONYLCYCLOHEXADIENYLIRON SALTS WITH O-SILYLATED ENOLATES, ALLYL SILANES AND ASPECTS OF THEIR SYNTHETIC EQUIVALENTS
Birch, Arthur J.,Kelly, Lawrence F.,Narula, Acharan S.
, p. 1813 - 1824 (2007/10/02)
Efficient C-C bond formation results during reactions of O-silylated enolates and allyltrialkylsilanes with a range of tricarbonylcyclohexadienyliron salts to give tricarbonylcyclohexadieneiron complexes in good to excellent yields.This represents a new a
ORGANOMETALLICS IN ORGANIC SYNTHESIS: TRICARBONYL-(3-METHOXYCYCLOHEXA-2,4-DIEN-1-YL)-IRON(1+). A SYNTHETIC EQUIVALENT OF THE C-5 CATION OF CYCLOHEXENONE.
Kelly, Lawrence F.,Dahler, Peter,Narula, Acharan S.
, p. 1433 - 1436 (2007/10/02)
Tricarbonyl-(3-methoxycyclohexa-2,4-dien-1-yl)-iron(1+) PF6(1-) 2 reacts with a variety of nucleophiles to give 5-substituted cyclohex-2-enones. 2 is shown to be a useful precursor for a convergent synthesis of 5-substituted cyclohex-2-enones and to be sy
ORGANOMETALLIC COMPOUNDS IN ORGANIC SYNTHESIS. AN EQUIVALENT OF AROMATIC NUCLEOPHILIC SUBSTITUTION BY REACTIONS OF TRICARBONYLCYCLOHEXADIENYLIUMIRON SALTS WITH O-SILYLATED ENOLATES: A NOVEL ARYLATION IN THE 2-POSITION OF CARBONYL COMPOUNDS.
Kelly, Lawrence F.,Narula, Acharan S.,Birch, Arthur J.
, p. 2455 - 2458 (2007/10/02)
Tricarbonylcyclohexadienyliumiron salts are synthetically equivalent to specifically substituted phenyl cations.
