18407-84-6Relevant academic research and scientific papers
Competitive electrochemical synthesis of 1-methoxy-3,6-bis (trimethylsilyl) cyclohexa-1,4-diene, a ketoprofen precursor
Biran,Bordeau,Serein-Spirau,Leger-Lambert,Dunogues
, p. 1727 - 1733 (1993)
The synthesis of 1-methoxy-3,6-bis (trimethylsilyl) cyclohexa-1,4-diene, a ketoprofen precursor has been achieved from anisole by an electrochemical way using an undivided cell fitted with a sacrificial aluminium anode and a stainless steel cathode, with
Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones
Zhao, Liang,Wang, Jinlian,Zheng, Hongyan,Li, Yun,Yang, Ke,Cheng, Bin,Jin, Xiaojie,Yao, Xiaojun,Zhai, Hongbin
supporting information, p. 6378 - 6381 (2015/01/09)
A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.
Simple and practical routes to enantiomerically pure 5-(Trialkylsilyl)-2-cyclohexenones
Sarakinos, Georgios,Corey
, p. 811 - 814 (2008/02/12)
Formula presented Enantiomerically pure chiral 5-silylated 2-cyclohexenones are easily prepared in high yield using as a key step kinetic resolution with a commercially available lipase. Fully active enzyme can be recovered very efficiently for reuse. The
(R)- AND (S)-5-TRIMETHYLSILYL-2-CYCLOHEXENONE: A VERSATILE CHIRAL SOURCE FOR THE SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXANONE DERIVATIVES
Asaoka, Morio,Shima, Kunihisa,Takei, Hisashi
, p. 5669 - 5672 (2007/10/02)
5-Trimethylsilyl-2-cyclohexenone was synthesized from anisole and was successfully resolved to the optically pure form utilizing kinetic resolution method of the reaction with thiol in the presence of cinchonidine. (+)-α-curcumene was synthesized from (R)
