18407-84-6

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 100-66-3 methoxybenzene 

Downstream Products

• 244109-55-5 C₉H₁₆OSi 
• 116215-95-3 (S)-(+)-5-(trimethylsilyl)-2-cyclohexenone 
• 117825-94-2 5-(4-methoxyphenyl)cyclohex-2-enone 
• 35376-41-1 5-phenylcyclohex-2-en-1-one 
• 93468-27-0 5-benzyl-2-cyclohexen-1-one 
• 75413-34-2 5-(2-propenyl)-2-cyclohexen-1-one 
• 117825-92-0 trans-3-p-methoxyphenyl-5-(trimethylsilyl)-cyclohexanone 
• 122044-86-4 (3S,5R)-3-Methyl-5-trimethylsilanyl-cyclohexanone 
• 122044-83-1 1-Methyl-4-((1R,5R)-5-trimethylsilanyl-3-trimethylsilanyloxy-cyclohex-2-enyl)-benzene 
• 122047-05-6 [2-((1R,5R)-5-Trimethylsilanyl-3-trimethylsilanyloxy-cyclohex-2-enyl)-ethyl]-benzene 
• 122044-82-0 ((1R,5R)-5-Trimethylsilanyl-3-trimethylsilanyloxy-cyclohex-2-enyl)-benzene 
• 122044-85-3 (3R,5R)-3-Hexyl-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene 
• 122044-76-2 (3S,5R)-3-Phenethyl-5-trimethylsilanyl-cyclohexanone 
• 122044-84-2 (3R,5R)-3-tert-Butyl-5-trimethylsilanyl-1-trimethylsilanyloxy-cyclohexene 

Relevant academic research and scientific papers

Competitive electrochemical synthesis of 1-methoxy-3,6-bis (trimethylsilyl) cyclohexa-1,4-diene, a ketoprofen precursor

The synthesis of 1-methoxy-3,6-bis (trimethylsilyl) cyclohexa-1,4-diene, a ketoprofen precursor has been achieved from anisole by an electrochemical way using an undivided cell fitted with a sacrificial aluminium anode and a stainless steel cathode, with

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.

Simple and practical routes to enantiomerically pure 5-(Trialkylsilyl)-2-cyclohexenones

Formula presented Enantiomerically pure chiral 5-silylated 2-cyclohexenones are easily prepared in high yield using as a key step kinetic resolution with a commercially available lipase. Fully active enzyme can be recovered very efficiently for reuse. The

(R)- AND (S)-5-TRIMETHYLSILYL-2-CYCLOHEXENONE: A VERSATILE CHIRAL SOURCE FOR THE SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXANONE DERIVATIVES

5-Trimethylsilyl-2-cyclohexenone was synthesized from anisole and was successfully resolved to the optically pure form utilizing kinetic resolution method of the reaction with thiol in the presence of cinchonidine. (+)-α-curcumene was synthesized from (R)