754227-25-3

Basic information

• Product Name: Cyclobutanemethanol, 2,2-dimethyl-3-(1-methylethylidene)-, (1S)- (9CI)
• Synonyms: Cyclobutanemethanol, 2,2-dimethyl-3-(1-methylethylidene)-, (1S)- (9CI)
• CAS NO: 754227-25-3
• Molecular Formula: C10H18O
• Molecular Weight: 154.24932
• Product Categories: METHYL
• Mol File: 754227-25-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclobutanemethanol, 2,2-dimethyl-3-(1-methylethylidene)-, (1S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclobutanemethanol, 2,2-dimethyl-3-(1-methylethylidene)-, (1S)- (9CI)(754227-25-3)
• EPA Substance Registry System: Cyclobutanemethanol, 2,2-dimethyl-3-(1-methylethylidene)-, (1S)- (9CI)(754227-25-3)

Safety Data

• Hazardous Substances Data: 754227-25-3(Hazardous Substances Data)

Upstream product

• 827610-64-0 (1R,5S)-(+)-4,4,6,6-tetramethyl-3-oxabicyclo[3.1.1]heptan-2-one 
• 827610-65-1 (R)-(-)-2,2-dimethyl-3-(1-methylethylidene)cyclobutanecarboxylic acid 
• 827610-63-9 (1R,3S)-(-)-3-(1-hydroxy-1-methylethyl)-2,2-dimethylcyclobutanecarboxylic acid 
• 22571-78-4 (+)-cis-pinononoic acid 
• 827610-66-2 (1S,3R)-3-(1-hydroxy-1-methylethyl)-2,2-dimethylcyclobutanecarboxylic acid 
• 827610-67-3 (1S,5R)-4,4,6,6-tetramethyl-3-oxabicyclo[3.1.1]heptan-2-one 
• 288848-24-8 (1S,3R)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid 
• 827610-68-4 (S)-2,2-dimethyl-3-(1-methylethylidene)cyclobutanecarboxylic acid 

Relevant articles and documents

Attractant pheromone for the male pink hibiscus mealybug, Maconellicoccus hirsutus (Green) (Homoptera: Pseudococcidae)

A composition for attracting male pink hibiscus mealybugs which contains a carrier material or carrier and effective amount of (R)-lavandulyl (S)-2-methylbutanoate and (R)-maconelliyl (S)-2-methylbutanoate. Also a method for attracting male pink hibiscus mealybugs to an object or area, which method involves treating said object or area with effective amount of (R)-lavandulyl (S)-2-methylbutanoate and (R)-maconelliyl (S)-2-methylbutanoate. Cyclobutanes, 2,2-dimethyl-3-(1-methylethylidene)cyclobutanes, having the formula: wherein R1 is hydrogen, a C1-11 straight or branched alcohol, aldehyde, alkyl, ether (e.g. methanol, ethanal, 4-methylhexane, heptyloxymethane), or esters thereof with a C1-10 saturated or unsaturated, straight or branched acid (e.g., formic acid, acetic acid, 2-methylbutyric acid, 3-methyl-2-butenoic acid) and R2 is hydrogen, methyl, C1-10 saturated or unsaturated, straight or branched alkyl (e.g. hexane, isopropenyl, 4-methyl-4-pentene). A method of disrupting male pink hibiscus mealybug mating with female pink hibiscus mealybugs, involving exposing a pink hibiscus mealybug population to a composition containing a pink hibiscus mealybug mating disrupting effective amount of (R)-lavandulyl (S)-2-methylbutanoate and (R)-maconelliyl (S)-2-methylbutanoate, and optionally a carrier material or carrier.

Chiral synthesis of maconelliol: A novel cyclobutanoid terpene alcohol from pink hibiscus mealybug, Maconellicoccus hirsutus

The chiral synthesis of maconelliol, [2,2-dimethyl-3-(1-methylethylidene) cyclobutyl] methanol, the alcohol moiety of the major sex pheromone component isolated from the pink hibiscus mealybug, Maconellicoccus hirsutus, is described. The compound was synthesized in six steps from alpha-pinene and the key step is dehydration of 5 to 7 through the intermediate 6. The absolute configuration of the naturally occurring maconelliol was determined as R.