75471-08-8Relevant articles and documents
PHOTOCHEMICAL REACTIONS OF PHOSPHAALKENES
Meriem, Abdelkader,Majoral, Jean-Pierre,Revel, Monique,Navech, Jacques
, p. 1975 - 1978 (2007/10/02)
Photolysis of phosphaalkenes leads to an inversion of polarity of the phosphorus carbon double bond and to a cleavage into transient phosphinidene and carbene; unexpected alcoholysis of a PIII-C bond and the cycloaddition of a linear phosphaalkene on a diene are also reported.
SYNTHESE VON ARYL-DIALKYLAMINOALKYLIDENPHOSPHINEN - EIN NEUER ZUGANG ZU DERIVATEN DES ZWEIFACH-KOORDINIERTEN DREIBINDIGEN PHOSPHORS
Oehme,Leissring,Meyer
, p. 1141 - 1144 (2007/10/02)
Aromatic primary phosphines react with carboxylic acid amide acetals to give aryldialkylaminoalkylidenphosphines.Intensive 1H, 13C and 31P nmr studies prove the compounds to involve phosphorus in the trivalent dicoordinate state.