75471-07-7

Basic information

• Product Name: (E)-N,N-dimethyl-1-(phenylphosphanylidene)methanamine
• Synonyms: Methanamine, N,N-dimethyl-1-(phenylphosphinidene)-
• CAS NO: 75471-07-7
• Molecular Formula: C₉H₁₂NP
• Molecular Weight: 165.172
• Mol File: 75471-07-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E)-N,N-dimethyl-1-(phenylphosphanylidene)methanamine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N,N-dimethyl-1-(phenylphosphanylidene)methanamine(75471-07-7)
• EPA Substance Registry System: (E)-N,N-dimethyl-1-(phenylphosphanylidene)methanamine(75471-07-7)

Safety Data

• Hazardous Substances Data: 75471-07-7(Hazardous Substances Data)

Upstream product

• 25818-74-0 1,1-dichloromethyl-N,N-dimethylamine 
• 24103-44-4 bis(trimethylsilyl)phenylphosphine 
• 1186-70-5 bis(dimethylamino)methoxymethane 
• 638-21-1 phenylphosphane 
• 75471-08-8 2,4-Bis-(dimethylamino)-1,3-diphenyl-1,3-diphosphetan 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 3127-08-0 bis(hydroxymethyl)phenylphosphine 

Downstream Products

• 128342-55-2 2-dimethylamino-5-dimethoxyphosphoryl-6-isopropylidene-1-phenyl-1,2,3-λ³-phosphorine 
• 128342-56-3 2-dimethylamino-5-diethoxyphosphoryl-6-isopropylidene-1-phenyl-1,2,3-λ³-phosphorine 
• 87119-47-9 (4,5-Dimethyl-1-phenyl-1,2,3,6-tetrahydro-phosphinin-2-yl)-dimethyl-amine 
• 25818-74-0 1,1-dichloromethyl-N,N-dimethylamine 
• 38476-60-7 S,S-diphenyl-P-phenyldithiophosphonite 
• 538-51-2 benzylidene phenylamine 
• 68-12-2 N,N-dimethyl-formamide 
• 126004-71-5 (Ethyl-phenyl-phosphinoylmethyl)-dimethyl-amine 
• 87119-48-0 (4,5-Dimethyl-1-phenyl-1-thioxo-1,2,3,6-tetrahydro-1λ⁵-phosphinin-2-yl)-dimethyl-amine 
• 42451-95-6 1,2,3,4-tetraphenyl-1,2-dihydro-1,2-diphosphete 
• 1783-25-1 N₁,N₁-dimethyl-N₂-phenylformamidine 
• 80919-13-7 1,3-diphenyl-2,4-di(phenylimino)-1,3-diaza-2,4-diphosphetidine 
• 116333-12-1 1,4,5,6-tetrachloro-7,7-dimethoxy-3-dimethylamino-2-phenyl-2-phospha-5-norbornene 
• 758-16-7 N,N-dimethylthioformamide 

Relevant articles and documents

ELECTROCHEMICAL REDUCTION OF SOME COMPOUNDS OF TWO-COORDINATE PHOSPHORUS AND ARSENIC IN AN APROTIC MEDIUM

The electrochemical reduction of a series of compounds of two-coordinate phosphorus and arsenic with linear structure was investigated for the first time.The main polarographic characteristics indicate irreversibility of the electrode process and its complication by kinetic limitations.The products of controlled-potential electrolysis were analyzed, and schemes are presented for the electrochemical reduction, which consists in hydrogenation with cleavage of the P=E bond of most of the studied compounds (1,2, and 4) and in cleavage of the CAr-P bond in sterically hindered compound 3.The electrolysis products underwent further transformation in the presence of oxygen and moisture of air.Keywords: two-coordinate phosphorus; two-coordinate arsenic; electrochemical reduction; controlled-potential electrolysis; aprotic media; steric factors.

REACTION OF BIS(HYDROXYMETHYL)PHENYLPHOSPHINE WITH DIMETHYLFORMAMIDE DIMETHYLACETAL

-

THERMAL AND PHOTOCHEMICAL REACTIVITY OF PHOSPHAALKENES

-