75478-77-2Relevant academic research and scientific papers
STERIC AND POLAR EFFECTS IN FREE-RADICAL REACTIONS. - AN UNUSUAL TYPE OF AZOCOUPLING BY FREE RADICAL DECOMPOSITION OF DIAZONIUM SALTS
Citterio, Attilio,Minisci, Francesco,Albinati, Alberto,Bruckner, Sergio
, p. 2909 - 2910 (1980)
A new free-radical azocoupling has been accomplished by decomposition of diazonium salts with monoelectronic reducing agents in the presence of 4-methyl-3-penten-2-one.Steric and polar factors are responsible of the unusual behaviour.
