STERIC AND POLAR EFFECTS IN FREE-RADICAL REACTIONS. - AN UNUSUAL TYPE OF AZOCOUPLING BY FREE RADICAL DECOMPOSITION OF DIAZONIUM SALTS

DOI: 10.1016/S0040-4039(00)78641-2

Source and publish data:

Tetrahedron Letters p. 2909 - 2910 (1980)

Update date:2022-08-05

Topics:

Authors:

Citterio, Attilio

Minisci, Francesco

Albinati, Alberto

Bruckner, Sergio

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Article abstract of DOI:10.1016/S0040-4039(00)78641-2

A new free-radical azocoupling has been accomplished by decomposition of diazonium salts with monoelectronic reducing agents in the presence of 4-methyl-3-penten-2-one.Steric and polar factors are responsible of the unusual behaviour.

Full text of DOI:10.1016/S0040-4039(00)78641-2

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