75490-39-0

Usage

InChI:InChI=1/C13H17N/c1-11(9-13(2,3)10-14)12-7-5-4-6-8-12/h4-8,11H,9H2,1-3H3

Upstream product

• 2978-30-5 2,2-dimethylpent-4-enenitrile 
• 71-43-2 benzene 
• 100-42-5 styrene 
• 50654-53-0 2-lithio-2-methylpropionitrile 
• 74-88-4 methyl iodide 
• 98-83-9 isopropenylbenzene 
• 78-82-0 Isobutyronitrile 
• 78-67-1 2,2'-azobis(isobutyronitrile) 

Downstream Products

• 92036-36-7 α,α-Dimethyl-γ-phenyl-valeriansaeure 
• 92036-42-5 α.α-Dimethyl-γ-(p-mercaptophenyl)-valeriansaeure 
• 92042-38-1 α,α-Dimethyl-γ-(p-nitrophenyl)-valeriansaeure 
• 92197-54-1 α,α-Dimethyl-γ-(p-aminophenyl)-valeriansaeure 

Relevant academic research and scientific papers

Rate constants for the addition of the 2-cyano-2-propyl radical to alkenes in solution

Absolute rate constants for the addition of the 2-cyano-2-propyl radical to 26 alkenes CH2 = CXY at 315 K were determined in solution by time-resolved electron-spin-resonance spectroscopy. They vary with the alkene substituents from 30 M-1 s-1 to 7′010 M-1 s-1. For styrene the temperature dependence is given by log k/M-1 s-1 = 7.7 - 26.1/Θ where Θ = 2.303 RT in kJ/mol. An analysis of the substituent effects in terms of polar and enthalpic factors reveals a dominant influence of the overall reaction enthalpy.

Process for preparing phenyl butyronitriles and perfumery use of 2,2-dimethyl-4-phenyl valeronitrile

Described is the use in imparting, augmenting or enhancing aromas to or in perfume compositions, colognes and perfumed articles by admixing therewith an aroma imparting, augmenting or enhancing quantity of 2,2-dimethyl-4-phenyl valeronitrile defined accor