75495-80-6Relevant academic research and scientific papers
R-P-VERBRUECKTE EISEN-CLUSTER-HYDRIDE
Huttner, Gottfried,Schneider, Josef,Mohr, Gerhard,Seyerl, Joachim Von
, p. 161 - 170 (1980)
Trinuclear clusters RPFe3(CO)9H2 (R = Ph, p-C6H4OCH3, C6H11, t-Bu, CH2CH2CN) are obtained in fair yields by treatment of Fe3(CO)12 with primary phosphanes, RPH2.X-ray structure analysis of PhPFe3(CO)9H2 reveals a trigonal pyramidal frame-work for the cluster with an iron triangle at the base and the phosphorus atom at the apex.Two of the three Fe-Fe bonds are bridged by hydrogens.Reaction of C5H5(CO)2MnP(C6H5)H2 with Fe3(CO)12 gives an improved yield of the known trinuclear heterometallic cluster C5H5(CO)2MnFe2(CO)6PC6H5.
