Journal of Organometallic Chemistry p. 161 - 170 (1980)
Update date:2022-08-05
Topics:
Huttner, Gottfried
Schneider, Josef
Mohr, Gerhard
Seyerl, Joachim Von
Trinuclear clusters RPFe3(CO)9H2 (R = Ph, p-C6H4OCH3, C6H11, t-Bu, CH2CH2CN) are obtained in fair yields by treatment of Fe3(CO)12 with primary phosphanes, RPH2.X-ray structure analysis of PhPFe3(CO)9H2 reveals a trigonal pyramidal frame-work for the cluster with an iron triangle at the base and the phosphorus atom at the apex.Two of the three Fe-Fe bonds are bridged by hydrogens.Reaction of C5H5(CO)2MnP(C6H5)H2 with Fe3(CO)12 gives an improved yield of the known trinuclear heterometallic cluster C5H5(CO)2MnFe2(CO)6PC6H5.
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Doi:10.1016/S0040-4039(00)78614-X
(1980)Doi:10.1016/S0022-328X(00)98594-2
(1983)Doi:10.1021/jo00274a048
(1989)Doi:10.1016/0040-4039(91)80021-W
(1991)Doi:10.1039/b407008a
(2004)Doi:10.1021/jo062006y
(2007)
