755033-94-4Relevant academic research and scientific papers
Scope of AuCl3 in the activation of per-O-acetylglycals
Balamurugan, Rengarajan,Koppolu, Srinivasa Rao
, p. 8139 - 8142 (2009)
Gold(III)chloride in catalytic amounts activates 3,4,6-tri-O-acetyl-d-glucal, 3,4,6-tri-O-acetyl-d-galactal, and 3,4-di-O-acetyl-l-rhamnal efficiently. The activated species can be employed in the Ferrier reaction with different nucleophiles at ambient conditions. Attempts have been made to make β-anomer of the Ferrier product from anomeric-O-propargylated Ferrier product.
Microwave-induced, InCl3-catalyzed Ferrier rearrangement of acetylglycals: Synthesis of 2,3-unsaturated glycopyranosides
Das, Saibal Kumar,Reddy, K. Anantha,Roy, Joyita
, p. 1607 - 1610 (2007/10/03)
Indium(III) chloride catalyzed, microwave assisted Ferrier rearrangement on different per-O-acetylglycals leads to an efficient synthesis of 2,3-unsaturated O-glycosides in good to excellent yields.
