75526-85-1Relevant academic research and scientific papers
Synthesis and Dioxygen-binding Properties of Double-sided Porphyrinatoiron(II) Complexes bearing Covalently Bound Axial Imidazole
Tsuchida, Eishun,Komatsu, Teruyuki,Arai, Kenji,Nishide, Hiroyuki
, p. 2465 - 2469 (2007/10/02)
Double-sided porphyrinatoiron(II) complexes bearing covalently bound axial imidazole, 5--10,15,20-trisporphyrinatoiron(II) and 5-2-(3,3-dimethylbutyryloxy)-6-(5-imidazolylvaler
Synthesis and Charactarization of "Tailed Picket Fence" Porphyrins
Collman, James P.,Brauman, John I.,Doxsee, Kenneth M.,Halbert, Thomas R.,Bunnenberg, Edward,et al.
, p. 4182 - 4192 (2007/10/02)
The synthesis of "picket fence" porphyrin derivatives bearing covalently attached axial bases is described.The porphyrins have been well characterized, primarily as the iron(II) complexes, meso-tri(α,α,α-o-pivalamidophenyl)-β-o-5-(N-imidazolyl)valeramidophenylporphinatoiron(II) and meso-tri(α,α,α-o-pivalamidophenyl)-β-o-4-(N-imidazolyl)butyramidophenylporphyrinatoiron(II), by UV/visible, MCD, 1H NMR, and Moessbauer spectroscopy, magnetic susceptibility, and elemental analysis.Preliminary results of carbon monoxide binding studies are reported.
