75579-17-8Relevant academic research and scientific papers
PREPARATION AND PROPERTIES OF STABLE MONO-, TRIS-, TETRAKIS- OR HEXAKIS(PENTAHALOPHENYL)THALLIATE(III) COMPLEXES
Uson, R.,Laguna, A.,Abad, J. A.
, p. 265 - 270 (2007/10/02)
Reaction of TlR2X, TlX3 and - with RLi (R=C6F5 or C6Cl5) leads to derivatives containing anions of the types -, - or 3-.Reactions of TlCl3 with - lead to - (R=C6F5) or - (R=C6Cl5) while addition of X- (X=Br- or SCN-) to Tl(C6Cl5)3 gives -.All the novel anions were isolated as salts of bulky cations (Me4N, Bu4N, PPN or Ph3BzP).
