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Chlorobis(pentafluorophenyl)thallium(III) is a chemical compound with the formula TlCl(C6F5)2. It is a derivative of thallium, a heavy metal element, and features a central thallium(III) ion coordinated to two pentafluorophenyl ligands and one chloride ion. This organothallium compound is of interest in organometallic chemistry due to its potential applications in catalysis and material science. The pentafluorophenyl groups provide stability to the compound through strong π-back bonding with the thallium center. Chlorobis(pentafluorophenyl)thallium(III) is typically synthesized through the reaction of thallium(III) chloride with pentafluorobenzene, and it is a valuable precursor for the preparation of other thallium-containing compounds.

1813-39-4

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1813-39-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1813-39-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,1 and 3 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1813-39:
(6*1)+(5*8)+(4*1)+(3*3)+(2*3)+(1*9)=74
74 % 10 = 4
So 1813-39-4 is a valid CAS Registry Number.

1813-39-4Relevant academic research and scientific papers

Reactions of thallium(III) chloride with (aryl)silver(I) complexes. Crystal structure of (mes=mesityl)

Laguna, Antonio,Fernandez, Eduardo J.,Mendia, Aranzazu,Ruiz-Romero, M. Elena,Jones, Peter G.

, p. 201 - 206 (2007/10/02)

The arylsilver derivatives AgR (R=mesityl, C6F3H2, C6F5) react with TlCl3 to give arylthallium(III) complexes of the types , TlClR2 or TlR3.The structure of has been established by X-ray crystallography; it consists of

CHLOROBIS(POLYFLUOROPHENYL)THALLIUM(III) COMPLEXES AND THEIR REACTIONS WITH GOLD(I) AND TIN(II) COMPOUNDS

Uson, R.,Laguna, A.,Cuenca, T.

, p. 271 - 276 (2007/10/02)

The reaction of TlCl3 with RLi leads to complexes of the general formula TlR2Cl (R=C6F5, p-C6F4H, m-C6F4H, 2,4,6-C6F3H2, p-C6FH4 or m-CF3C6H4).Some of these undergo oxidative addition reactions with gold(I) complexes to give polyfluorophenyl derivatives of the types AuR2ClL and Au(C6F5)R2(tht) (tht=tetrahydrothiophen), and with SnCl2 to give oily materials from which stable solids of the general formula Q can be isolated by addition of QCl (Q=Et4N or Ph3BzP).

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